Abstract
The processes and products of the thermal transformations of a chelate complex, bis{N-[2-(allylaminomethyl)phenyl]-4-methylbenzenesulfamidato}copper(II), are studied using thermogravimetry, electron microscopy, microdiffraction of electrons, and IR spectroscopy. The kinetics of the process bears a dispersive character. Depending on the conditions of thermolysis (atmosphere, temperature mode), composite materials filled with copper or copper sulfide nanoparticles are formed as solid products.
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ACKNOWLEDGMENTS
This work was performed with the use of the equipment of the Analytical Center for Collective Use of the Institute of Problems of Chemical Physics, Russian Academy of Sciences.
Funding
This work was performed in line with state tasks (state registration numbers АААА-А19-119101690058-9 and 0089-2019-0012). The synthesis of the ligand and copper complex and the elucidation of their structure were executed by A.S. Burlov with the financial support from the base part of a state task (project 4.5388.2017/8.9).
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Translated by E. Boltukhina
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Chukanov, N.V., Larikova, T.S., Dremova, N.N. et al. Method of Preparation of Composite Materials Filled with Copper and Copper Sulfide Nanoparticles. Russ. J. Phys. Chem. B 14, 323–331 (2020). https://doi.org/10.1134/S1990793120020037
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DOI: https://doi.org/10.1134/S1990793120020037