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Reactions of 2-Phosphonylethynylated 2-(Arylamino)malonates with Some Bases

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Abstract

The reaction of dialkyl 2-[(dialkoxyphosphoryl)ethynyl]-2-(arylamino)malonates with bases (CH3COOK, t-BuOK) can serve as a method for preparing original diphosphonylated 2,3-dihydro-1H-pyrroles and 4-phosphonylated 1-azabuta-1,3-dienes. A probable scheme for the formation of the obtained new compounds is proposed.

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Funding

This work was financially supported by the Russian Foundation for Basic Research (grant no. 19-03-00365) in the frame of the basic part of the governmental task of the Ministry of Education and Science of the Russian Federation (no. 4.5554.2017/8.9) using the equipment of the Engineering Center of the St. Petersburg State Institute of Technology.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    A. V. Egorova, N. B. Viktorov & A. V. Dogadina

  2. Scientific Research Center for Environmental Safety of the Russian Academy of Sciences, St. Petersburg, Russia

    A. V. Egorova

  3. St. Petersburg State University, St. Petersburg, Russia

    G. L. Starova

Authors
  1. A. V. Egorova
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  2. N. B. Viktorov
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  3. G. L. Starova
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  4. A. V. Dogadina
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Corresponding author

Correspondence to A. V. Dogadina.

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No conflict of interest was declared by the authors.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 9, pp. 1352–1360.

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Egorova, A.V., Viktorov, N.B., Starova, G.L. et al. Reactions of 2-Phosphonylethynylated 2-(Arylamino)malonates with Some Bases. Russ J Gen Chem 89, 1765–1771 (2019). https://doi.org/10.1134/S1070363219090068

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  • DOI: https://doi.org/10.1134/S1070363219090068

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