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Synthesis and structures of the six-coordinate donor-acceptor complexes R3(C6H4O2)Sb…L (R=Ph, L=OSMe2 or ONC5H5; R=Me, L=ONC5H5 or NC5H5) and R3(C2H4O2)Sb…L (R=Ph, L=ONC5H5; R=Cl or C6F5, L=OPPh3)

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

One-pot oxidation of R3Sb (R=Ph, Me, Cl, or C6F5) withtert-butyl hydroperoxide in the presence of 1,2-diols and monodentate donor compounds was studied. The structures of the resulting neutral organic donor-acceptor SbV complexes, Ph3(C6H4O2)Sb…OSMe2, Ph3(C6H4O2)Sb…ONC5H5, Me3(C6H4O2)Sb…ONC5H5, Me3(C6H4O2)Sb…NC5H5, Ph3(C2H4O2)Sb…ONC5H5, and Cl(C6F5)2(C2H4O2)Sb…OPPh3, were established by X-ray diffraction analysis. In these complexes, the coordination environment about the Sb atoms is a distorted octahedron. The Sb−O(N) distances and the Sb−O−E angles (E=S, N, or P) vary over wide ranges.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    G. K. Fukin, L. N. Zakharov & G. A. Domrachev

  2. Department of Chemistry, N. I. Lobachevsky Nizhnii Novgorod State University, 23a prosp. Gagarina, 603600, Nizhnii Novgorod, Russian Federation

    A. Yu. Fedorov, S. N. Zaburdyaeva & V. A. Dodonov

Authors
  1. G. K. Fukin
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  2. L. N. Zakharov
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  3. G. A. Domrachev
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  4. A. Yu. Fedorov
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  5. S. N. Zaburdyaeva
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  6. V. A. Dodonov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1744–1754, September, 1999.

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Fukin, G.K., Zakharov, L.N., Domrachev, G.A. et al. Synthesis and structures of the six-coordinate donor-acceptor complexes R3(C6H4O2)Sb…L (R=Ph, L=OSMe2 or ONC5H5; R=Me, L=ONC5H5 or NC5H5) and R3(C2H4O2)Sb…L (R=Ph, L=ONC5H5; R=Cl or C6F5, L=OPPh3). Russ Chem Bull 48, 1722–1732 (1999). https://doi.org/10.1007/BF02494820

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  • DOI: https://doi.org/10.1007/BF02494820

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