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Unusual Reaction of Sodium 1,6-Dioxo-2,4-alkadiene-3,4-diolates under Acid Hydrolysis Conditions

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Abstract

The reaction of sodium 1,6-dioxo-2,4-alkadiene-3,4-diolates with HCl solution afforded unexpected hydrolysis products, namely (2Z)-2-hydroxy-4-oxobut-2-enoic (2,4-dioxobutanoic) acid esters. The structural features of the synthesized compounds were discussed on the basis of IR, 1H NMR spectroscopy, mass spectrometry and X-ray diffraction analysis data.

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Authors and Affiliations

  1. All-Russian Research Institute of Phytopathology, ul. Institut 5, Bol’shiye Vyazemy, Moscow oblast, 143050, Russia

    P. P. Mukovoz

  2. Postovskii Institute of Organic Synthesis, Yekaterinburg, Russia

    P. A. Slepukhin & I. N. Ganebnykh

  3. Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, Russia

    P. A. Slepukhin, I. N. Ganebnykh & O. S. El’tsov

  4. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    E. A. Danilova

Authors
  1. P. P. Mukovoz
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  2. P. A. Slepukhin
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  3. I. N. Ganebnykh
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  4. O. S. El’tsov
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  5. E. A. Danilova
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Corresponding author

Correspondence to P. P. Mukovoz.

Additional information

Original Russian Text © P.P. Mukovoz, P.A. Slepukhin, I.N. Ganebnykh, O.S. El’tsov, E.A. Danilova, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 10, pp. 1590–1594.

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Mukovoz, P.P., Slepukhin, P.A., Ganebnykh, I.N. et al. Unusual Reaction of Sodium 1,6-Dioxo-2,4-alkadiene-3,4-diolates under Acid Hydrolysis Conditions. Russ J Gen Chem 88, 2039–2043 (2018). https://doi.org/10.1134/S107036321810002X

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  • DOI: https://doi.org/10.1134/S107036321810002X

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