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Synthesis and Structure of Disodium 1,2-Bis(2-oxocycloalkylidene)ethane-1,2-diolates and Disodium 4-Alkoxy-4-oxo-1-(2-oxocycloalkylidene)but-2-ene-1,2-diolates

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Abstract

Two-stage condensation of cycloalkyl ketones with dimethyl oxalate or alkyl acetates with dialkyl oxalates and cycloalkyl ketones produced disodium 1,2-bis(2-oxocycloalkylidene)ethane-1,2-diolates and disodium 4-alkoxy-4-oxo-1-(2-oxocycloalkylidene)but-2-ene-1,2-diolates, respectively. The structural features of the obtained compounds were discussed on the basis of their IR, 1H NMR spectroscopy, and mass spectrometry data.

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Authors and Affiliations

  1. All-Russian Research Institute of Phytopathology, ul. Institut 5, Bol’shiye Vyazemy, Moscow oblast’, 143050, Russia

    P. P. Mukovoz, E. S. Dankovtseva, V. P. Mukovoz, V. V. Abramova & N. A. Chigrineva

  2. Orenburg State University, Orenburg, Russia

    V. V. Abramova & N. A. Chigrineva

  3. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    E. A. Danilova

Authors
  1. P. P. Mukovoz
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  2. E. S. Dankovtseva
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  3. V. P. Mukovoz
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  4. V. V. Abramova
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  5. N. A. Chigrineva
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  6. E. A. Danilova
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Corresponding author

Correspondence to P. P. Mukovoz.

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Russian Text © P.P. Mukovoz, E.S. Dankovtseva, V.P. Mukovoz, V.V. Abramova, N.A. Chigrineva, E.A. Danilova, 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 2, pp. 223–229.

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Mukovoz, P.P., Dankovtseva, E.S., Mukovoz, V.P. et al. Synthesis and Structure of Disodium 1,2-Bis(2-oxocycloalkylidene)ethane-1,2-diolates and Disodium 4-Alkoxy-4-oxo-1-(2-oxocycloalkylidene)but-2-ene-1,2-diolates. Russ J Gen Chem 89, 224–229 (2019). https://doi.org/10.1134/S1070363219020099

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  • DOI: https://doi.org/10.1134/S1070363219020099

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