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Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVIII. Magnetic susceptibility and ESR spectra of Bi2BaNb2–2xMn2xO9–δ solid solutions with layered perovskite-like structure

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Abstract

On the basis of the data of ESR and magnetic susceptibility of Bi2BaNb2–2xMn2xO9–δ solid solutions with perovskite-like structure ferro- and aniferromagnetic bonded dimers, trimers, and tetramers of Mn(II), Mn(III), and Mn(IV) atoms in various valence states were found. The distribution of aggregates and exchange parameters in the clusters were calculated as a function of fraction x of manganese atoms in the solid solutions. In the ESR spectra of diluted solid solutions there are absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    N. V. Chezhina, D. A. Korolev & A. V. Fedorova

  2. Sorokin Syktyvkar State University, Oktyabr’skii pr. 55, Syktyvkar, 167001, Russia

    N. A. Zhuk, L. S. Feltsinger & E. A. Pryanishnikova

  3. Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    V. P. Lutoev & B. A. Makeev

Authors
  1. N. V. Chezhina
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  2. D. A. Korolev
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  3. A. V. Fedorova
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  4. N. A. Zhuk
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  5. L. S. Feltsinger
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  6. E. A. Pryanishnikova
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  7. V. P. Lutoev
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  8. B. A. Makeev
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Corresponding author

Correspondence to N. A. Zhuk.

Additional information

For communication XVII, see [1].

Original Russian Text © N.V. Chezhina, D.A. Korolev, A.V. Fedorova, N.A. Zhuk, L.S. Feltsinger, E.A. Pryanishnikova, V.P. Lutoev, B.A. Makeev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 11, pp. 1781–1788.

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Chezhina, N.V., Korolev, D.A., Fedorova, A.V. et al. Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVIII. Magnetic susceptibility and ESR spectra of Bi2BaNb2–2xMn2xO9–δ solid solutions with layered perovskite-like structure. Russ J Gen Chem 87, 2525–2532 (2017). https://doi.org/10.1134/S1070363217110032

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  • DOI: https://doi.org/10.1134/S1070363217110032

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