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Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVII.1 Magnetic properties of Bi5Nb3–3xMn3xO15–δ solid solutions

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Abstract

A monoclinic distortion of tetragonal cell was found in the solid solutions with layered perovskite-like structure [Bi5Nb3–3xMn3xO15–δ (0.005 < х ≤ 0.06)]. In the ESR spectra absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms are recorded. The studies of magnetic susceptibility of the Bi5Nb3–3xMn3xO15–δ solid solutions revealed the formation of ferro- and antiferromagnetically bonded dimers of Mn(II), Mn(III), and Mn(IV) atoms. The exchange parameters in dimers and the distribution of paramagnetic manganese atoms in dependence to solid solution concentrations were calculated.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    N. V. Chezhina, D. A. Korolev & A. V. Fedorova

  2. Syktyvkar State University, Syktyvkar, Russia

    N. A. Zhuk, M. V. Filippova & L. S. Feltsinger

  3. Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    V. P. Lutoev, B. A. Makeev & S. S. Shevchuk

  4. Institute of Biology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    A. N. Nizovtsev

Authors
  1. N. V. Chezhina
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  2. D. A. Korolev
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Correspondence to N. V. Chezhina.

Additional information

Original Russian Text © N.V. Chezhina, D.A. Korolev, A.V. Fedorova, N.A. Zhuk, M.V. Filippova, L.S. Feltsinger, V.P. Lutoev, B.A. Makeev, S.S. Shevchuk, A.N. Nizovtsev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 10, pp. 1589–1596.

For communication XVI, see [1].

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Chezhina, N.V., Korolev, D.A., Fedorova, A.V. et al. Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVII.1 Magnetic properties of Bi5Nb3–3xMn3xO15–δ solid solutions. Russ J Gen Chem 87, 2251–2257 (2017). https://doi.org/10.1134/S1070363217100012

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  • DOI: https://doi.org/10.1134/S1070363217100012

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