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Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XIV. Magnetic behavior of Bi2BaNb2–2x Fe2x O9–δ solid solutions

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Abstract

Magnetic susceptibility and ESR properties of iron-containing Bi2BaNb2–2x Fe2x O9–δ solid solutions with layered perovskite-like structure have been studied. In the diluted solid solutions, iron atoms are combined into Fe(III) dimers and tetramers with antiferro- and ferromagnetic exchange types. The exchange parameters and the distribution of aggregates in the solid solutions have been calculated as functions of the paramagnetic atoms fractions.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskaya nab. 7–9, St. Petersburg, 199034, Russia

    N. V. Chezhina, D. A. Korolev & A. V. Fedorova

  2. Syktyvkar State University, Syktyvkar, Russia

    N. A. Zhuk & V. A. Butin

  3. Institute of Geology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    V. P. Lutoev, B. A. Makeev & S. S. Shevchuk

  4. Institute of Biology, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    A. N. Nizovtsev

Authors
  1. N. V. Chezhina
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  2. D. A. Korolev
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  3. A. V. Fedorova
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  4. N. A. Zhuk
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  5. V. A. Butin
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  6. V. P. Lutoev
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  7. B. A. Makeev
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  8. S. S. Shevchuk
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  9. A. N. Nizovtsev
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Corresponding author

Correspondence to N. V. Chezhina.

Additional information

Original Russian Text © N.V. Chezhina, D.A. Korolev, A.V. Fedorova, N.A. Zhuk, V.A. Butin, V.P. Lutoev, B.A. Makeev, S.S. Shevchuk, A.N. Nizovtsev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 2, pp. 186–193.

For communication XIII, see [1].

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Chezhina, N.V., Korolev, D.A., Fedorova, A.V. et al. Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XIV. Magnetic behavior of Bi2BaNb2–2x Fe2x O9–δ solid solutions. Russ J Gen Chem 87, 168–174 (2017). https://doi.org/10.1134/S1070363217020037

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  • DOI: https://doi.org/10.1134/S1070363217020037

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