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Reaction of transsilylation of N-methyl-N-trimethylsilylacetamide with silanes ClCH2SiR1R2Cl

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Abstract

The reaction of N-methyl-N-trimethylsilylacetamide with silanes ClCH2SiR1R2Cl (R1, R2 = H, Me; H, Ph; Ph2) leads to the formation of (O→Si) chelate compounds with pentacoordinate silicon: N-[chloro(methyl)-silyl]methyl-, N-[chloro(phenyl)silyl]methyl-, and N-[chloro(diphenyl)silyl]methyl-N-methylacetamides. From the data of multinuclear NMR spectroscopy, the intermediates of the reaction of N-methyl-N-trimethylsilylacetamide with ClCH2SiPhHCl and ClCH2SiPh2Cl are stable in CDCl3 solution at room temperature during several days and slowly rearrange to the final (O–Si) chelate compounds.

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Authors and Affiliations

  1. A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. F. Lazareva & I. М. Lazarev

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  1. N. F. Lazareva
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  2. I. М. Lazarev
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Correspondence to N. F. Lazareva.

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Original Russian Text © N.F. Lazareva, I.М. Lazarev, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 8, pp. 1309–1314.

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Lazareva, N.F., Lazarev, I.М. Reaction of transsilylation of N-methyl-N-trimethylsilylacetamide with silanes ClCH2SiR1R2Cl. Russ J Gen Chem 87, 1721–1726 (2017). https://doi.org/10.1134/S107036321708014X

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  • DOI: https://doi.org/10.1134/S107036321708014X

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