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Mild regioselective iodination of pyrazoles using n-butyltriphenylphosphonium peroxodisulfate

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Abstract

A practical, efficient and inexpensive method of synthesis of iodopyrazoles by the reaction of pyrazoles with iodine using n-butyltriphenylphosphonium peroxodisulfate as an oxidant at room temperature is reported. The use of n-butyltriphenylphosphonium peroxodisulfate is feasible due to its easy preparation and handling, high stability and activity.

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References

  1. Badri, R., Adlu, M., and Mohammadi, M.K., Arab. J. Chem., 2015, vol. 8, p. 62. doi 10.1016/j.arabjc.2011.01.006.

    Article  CAS  Google Scholar 

  2. Gorjizadeh, M. and Afshari, M., Bulg. Chem.Commun., 2015, vol. 47, p. 673. doi 10.5012/bkcs.2013.34.6.1751.

    Google Scholar 

  3. Sapurina, I. and Stejskal, J., Russ. J. Gen. Chem., 2012, vol. 82, p. 256. doi 10.1134/S1070363212020168.

    Article  CAS  Google Scholar 

  4. Badri, R. and Gorjizadeh, M., Chin. Chem. Lett., 2009, vol. 20, p. 1439. doi 10.1016/j.cclet.2009.06.017

    Article  CAS  Google Scholar 

  5. Rodríguez-Franco, M.I., Dorronsoro, I., Hernández-Higueras, A.I., and Antequera, G., Tetrahedron Lett., 2001, vol. 42, p. 863. doi 10.1016/S0040-4039(00) 02136-5.

    Article  Google Scholar 

  6. Cheng, D.P., Chen, Z.C., and Zheng, Q.G., Synth. Commun., 2003, vol. 33, p. 2671. doi 10.1081/SCC-120021987.

    Article  CAS  Google Scholar 

  7. Gorjizadeh, M. and Abdollahi-Alibeik, M., Chin. Chem. Lett., 2011, vol. 22, p. 61. doi 10.1016/j.cclet.2010.07.022.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shooshtar Branch, Islamic Azad University, Daneshgah Shooshtar, Iran

    M. Gorjizadeh & M. Afshari

  2. Department of Chemistry, Dezful Branch, Islamic Azad University, Dezful, Iran

    M. Naseh

Authors
  1. M. Gorjizadeh
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  2. M. Afshari
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  3. M. Naseh
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Correspondence to M. Gorjizadeh.

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The text was submitted by the authors in English.

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Gorjizadeh, M., Afshari, M. & Naseh, M. Mild regioselective iodination of pyrazoles using n-butyltriphenylphosphonium peroxodisulfate. Russ J Gen Chem 86, 1931–1934 (2016). https://doi.org/10.1134/S1070363216080259

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  • DOI: https://doi.org/10.1134/S1070363216080259

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