Skip to main content
SpringerLink
Log in

Complex formation of β-brominated tetraphenylporphyrins and metal exchange of their cadmium complexes with d-metal salts in dimethylformamide

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Complex formation of zinc and copper(II) acetates with tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in N,N-dimethylformamide has been studied. The rate constants determined in the study of the complex formation and the metal exchange reactions have been compared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Berezin, B.D. and Koifman, O.I., Russ. Chem. Rev., 1973, vol. 42, no. 11, p. 922. DOI: 10.1070/RC1973v042n11ABEH002775.

    Article  Google Scholar 

  2. Brigas, A.F., Costa, A.M., Serra, A.C., and Pires, C., J. Pharm. Bioallied Sci., 2011, vol. 3, no. 2, p. 294. DOI: 10.4103/0975-7406.80770.

  3. Porphyrins and Metalloporphyrins, Smith, K.M., Ed., New York: Elsevier, 1975, p. 233.

  4. Jian-Zhong Zou, Zheng Xu, Ming Li, Xico-Zeng You, Acta Crystallogr., 1995, vol. 51, p. 760. DOI: 10.1107/S0108270194000053.

    Google Scholar 

  5. Senge, M.O., Forsyth, T.P., Nguyen, L.T., and Smith, K.M., Angew. Chem. Int. Ed., 1994, vol. 33, nos. 23–24, p. 2485. DOI: 10.1002/anie.199424851.

    Google Scholar 

  6. Berezin, B.D., J. Appl. Spectrosc., 1999, vol. 66, no. 4, p. 521. DOI: 10.1007/BF02675379.

    Article  CAS  Google Scholar 

  7. Berezin, B.D., Karmanova, T.V., Gromova, T.V., Syrbu, S.A., and Semeikin, A.S., Russ. J. Coord. Chem., 2002, vol. 28, no. 9, p. 608. DOI: 10.1023/A:1020030714257.

    Article  CAS  Google Scholar 

  8. Gao, G.-Y., Ruppel, J.V., Allen, D.B., Chen, Y., and Zhang, X.P., J. Org. Chem., 2007, vol. 72, p. 9060. DOI: 10.1021/jo701476m.

    Article  CAS  Google Scholar 

  9. Kumar, P.K., Bhyrappa, P., and Varghese, B., Tetrahedron Lett., 2003, vol. 44, p. 4849. DOI: 10.1016/S0040-4039(03)01143-2.

    Article  CAS  Google Scholar 

  10. Bhyrappa, P. and Krishun, V., Inorg. Chem., 1991, vol. 30, no. 2, p. 239. DOI: 10.1021/ic00002a018.

    Article  CAS  Google Scholar 

  11. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Montgomery, J.A., Vreven, T., Kudin, K.N., Burant, J.C., Millam, J.M., Iyengar, S.S., Tomasi, J., Barone, V., Mennucci, B., Cossi, M., Scalmani, G., Rega, N., Petersson, G.A., Nakatsuji, H., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Klene, M., Knox, X, Li, J.E., Hratchian, H.P., Cross, J.B., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R.E., Yazyev, O., Austin, A.J., Cammi, R., Pomelli, C., Ochterski, J.W., Ayala, P.Y., Morokuma, K., Voth, G.A., Salvador, P., Dannenberg, J.J., Zakrzewski, V.G., Dapprich, S., Daniels, A.D., Strain, M.C., Farkas, O., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Ortiz, J.V., Cui, Q., Baboul, A.G., Clifford, S., Cioslowski, J., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Martin, R.L., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Challacombe, M., Gill, P.M.W., Johnson, B., Chen, W., Wong, M.W., Gonzalez, C., and Pople, J.A., GAUSSIAN, Inc., Pittsburgh PA, 2003.

    Google Scholar 

  12. Karmanova, T.V., Gromova, T.V., Berezin, B.D., Semeikin, A.S., and Syrbu, S.A., Russ. J. Gen. Chem., 2001, vol. 71, no. 5, p. 803. DOI: 10.1023/A: 1012386124803.

    Article  CAS  Google Scholar 

  13. Berezin, B.D., Coordination Compounds of Porphyrins and Phthalocyanines, New York; Toronto: Wiley, 1981.

    Google Scholar 

  14. Bhyrappa, P., Nethaji, M., and Krishun, V., Chem. Lett., 1993, p. 869. DOI: 10.1246/cl.1993.869.

    Google Scholar 

  15. Porphyrin Handbook, Smith, K., Kadish, K., and Guillard, R., Eds., New York: Academic Press, 2000, vol. 3, p. 129.

  16. Grant, C. and Hambright, P., J. Am. Chem. Soc., 1969, vol. 91, no. 15, p. 4195. DOI: 10.1021/ja01043a030.

    Article  CAS  Google Scholar 

  17. Reid, J. and Hambright, P., Inorg. Chim. Acta, 1979, vol. 33, p. L135. DOI: 10.1016/S0020-1693(00)89424-4.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    O. V. Maltseva, S. V. Zvezdina, N. V. Chizhova & N. Zh. Mamardashvili

Authors
  1. O. V. Maltseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Zvezdina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Chizhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Zh. Mamardashvili
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. V. Maltseva.

Additional information

Original Russian Text © O.V. Maltseva, S.V. Zvezdina, N.V. Chizhova, N.Zh. Mamardashvili, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 1, pp. 110–117.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Maltseva, O.V., Zvezdina, S.V., Chizhova, N.V. et al. Complex formation of β-brominated tetraphenylporphyrins and metal exchange of their cadmium complexes with d-metal salts in dimethylformamide. Russ J Gen Chem 86, 102–109 (2016). https://doi.org/10.1134/S1070363216010187

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363216010187

Keywords

Search

Navigation