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Metal Exchange Reactions of o,o′-Dihalosubstituted Cd(II) Tetraphenylporphyrinates with d-Metal Salts in DMF

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Abstract

The metal exchange reactions of Cd(II)-5,10,15,20-tetra(2,6-dichlorophenyl) porphyrin and Cd(II)5,10,15,20-tetra(2,6-difluorophenyl) porphyrin with Zn(II) and Co(II) cations in dimethylformamide were studied by the spectrophotometric method. The kinetic parameters of the metal exchange reaction were calculated and a possible stoichiometric mechanism of the process is proposed. The metal exchange reactions of 2,6-dihalogenated cadmium porphyrins with Zn(II) and Co(II) chlorides and acetates in dimethylformamide were investigated by the sampling method. Zn(II)- and Co(II)-complexes with 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin and 5,10,15,20-tetra(2,6-difluorophenyl) pophirin were synthesized and identified by UV-Vis, 1H NMR spectroscopy and mass spectrometry methods.

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REFERENCES

  1. Grant, C. and Hembright, P., J. Am. Chem. Soc., 1969, vol. 91, no. 15, p. 4195. https://doi.org/10.1021/ja01043a030

    Article  CAS  Google Scholar 

  2. Hambright, P., Russ. Chem. Rev., 1977, vol. 46, no. 7, p. 1207.

    CAS  Google Scholar 

  3. Hambright, P., in Porphyrin Handbook, Smith, K., Kadish, K., and Guillard, R., Eds., New York: Academic Press, 2000, vol. 3, p. 129.

  4. Berezin, B.D., Rumyantseva, S.V., and Berezin, M.B., Russ. J. Coord. Chem., 2004, vol. 30, no. 4, p. 291. https://doi.org/10.1023/B:RUCO.0000022806.85114.93

    Article  CAS  Google Scholar 

  5. Berezin, M.B., Zvezdina, S.V., and Berezin, B.D., Russ. J. Coord. Chem., 2007, vol. 33, no. 7, p. 488. doi:10.1134/S1070328407070032

    Article  CAS  Google Scholar 

  6. Zvezdina, S.V., Berezin, M.B., and Berezin, B.D., Russ. J. Coord. Chem., 2010, vol. 36, no. 12, p. 913. https://doi.org/10.1134/S1070328410120080

    Article  CAS  Google Scholar 

  7. Linstead, R.P. and Weiss, F.T., J. Chem. Soc., 1950, p. 2975. https://doi.org/10.1039/JR9500002975

  8. Chizhova, N.V., Khelevina, О.G., and Berezin, B.D., Russ. J. Gen. Chem., 2003, vol. 73, no. 10, p. 1645. https://doi.org/10.1023/B:RUGC.0000016039.52090.d2

    Article  CAS  Google Scholar 

  9. Stuzhin, P.A., Ivanova, S.S., Koifman, O.I., Petrov, O.A., and Nazarova, A., Inorg. Chem. Commun., 2014, vol. 49, p. 72. https://doi.org/10.1016/j.inoche.2014.09.002

    Article  CAS  Google Scholar 

  10. Chizhova, N.V., Ivanova, J.B., Rusanov, A.I., Khrushkova, J.V., and Mamardashvili, N.Z., Russ. J. Org. Chem., 2019, vol. 55, no. 5, p. 655. https://doi.org/10.1134/S1070428019050129

    Article  CAS  Google Scholar 

  11. Hötger, D., Abufager, P., Morchutt, C., Alexa, P., Grumelli, D., Dreiser, J., Stepanow, S., Gambardella, P., Busnengo, H., Etzkorn, M., Gutzler, R., and Kerna, K., Nanoscale, 2018, vol. 10, p. 21116. https://doi.org/10.1039/c8nr04786c

    Article  CAS  PubMed  Google Scholar 

  12. Zvezdina, S.V., Berezin, M.B., and Berezin, B.D., Russ. J. Inorg. Chem., 2007, vol. 52, no. 8, p. 1269. https://doi.org/10.1134/S0036023607080177

    Article  Google Scholar 

  13. Zvezdina, S.V., Chizhova, N.V., and Mamardashvili, N.Z., Russ. J. Gen. Chem., 2020, vol. 90, no. 11, p. 2105. https://doi.org/10.1134/S1070363220110134

    Article  CAS  Google Scholar 

  14. Berezin, B.D. and Golubchikov, O.A., Koordinatsionnaya khimiya sol’vatokompleksov solei perekhodnykh metallov (Coordination Chemistry of Solvate Complexes of Transition Metal Salts), Moscow: Nauka, 1992.

  15. Chizhova, N.V., Kumeev, R.S., and Mamardashvili, N.Z., Russ. J. Inorg. Chem., 2013, vol. 58, no. 6, p. 740. https://doi.org/10.1134/S0036023613060089

    Article  CAS  Google Scholar 

  16. Zvezdina, S.V. and Mamardashvili, N.Zh., Russ. J. Coord. Chem., 2012, vol. 38, no. 5, p. 323. https://doi.org/10.1134/S1070328412050120

    Article  CAS  Google Scholar 

  17. Adler, A.D., Longo, F.R., Kampas, F., and Kim, J., J. Inorg. Nucl. Chem., 1970, vol. 32, p. 2443. https://doi.org/10.1016/0022-1902(70)80535-8

    Article  CAS  Google Scholar 

  18. Chizhova, N.V., Mamardashvili, G.M., Dmitrieva, O.A., Mamardashvili, N.Z., and Koifman, O.I., Macroheterocycles, 2019, vol. 12, no. 4, p. 364. https://doi.org/10.6060/mhc190556m

    Article  CAS  Google Scholar 

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Funding

This work was financially supported by the Russian Foundation for Basic Research (project no. 19-03-00078 A) with using of equipment of the Upper Volga Regional Center for Physicochemical Research.

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Authors and Affiliations

  1. G.A. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    S. V. Zvezdina, N. V. Chizhova & N. Z. Mamardashvili

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  1. S. V. Zvezdina
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  2. N. V. Chizhova
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  3. N. Z. Mamardashvili
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Correspondence to S. V. Zvezdina.

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Additional information

Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 8, pp. 1261–1268 https://doi.org/10.31857/S0044460X2108014X.

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Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Metal Exchange Reactions of o,o′-Dihalosubstituted Cd(II) Tetraphenylporphyrinates with d-Metal Salts in DMF. Russ J Gen Chem 91, 1526–1532 (2021). https://doi.org/10.1134/S1070363221080144

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