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Synthesis and spectral properties of β-bromo-substituted nickel(II) tetraphenylporphyrins

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Abstract

Bromination of (5,10,15,20-tetraphenylporphyrinato)nickel(II) with N-bromosuccinimide in chloroform and chloroform–dimethylformamide mixture and complexation of 2-bromo-5,10,15,20-tetraphenylporphyrin and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with nickel(II) acetate in dimethylformamide have been studied. The resulting nickel(II) complexes with mono-, tetra-, and octabromo-5,10,15,20-tetraphenylporphyrins have been identified by electronic absorption, IR, 1H NMR, and mass spectra.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153040, Russia

    N. V. Chizhova, O. V. Mal’tseva, N. Zh. Mamardashvili & O. I. Koifman

  2. Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    A. V. Konakova & O. I. Koifman

  3. Research Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry and Technology, Sheremetevskii pr. 7, Ivanovo, 153000, Russia

    O. I. Koifman

Authors
  1. N. V. Chizhova
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  2. A. V. Konakova
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  3. O. V. Mal’tseva
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  4. N. Zh. Mamardashvili
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  5. O. I. Koifman
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Corresponding author

Correspondence to N. V. Chizhova.

Additional information

Original Russian Text © N.V. Chizhova, A.V. Konakova, O.V. Mal’tseva, N.Zh. Mamardashvili, O.I. Koifman, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 7, pp. 1080–1083.

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Chizhova, N.V., Konakova, A.V., Mal’tseva, O.V. et al. Synthesis and spectral properties of β-bromo-substituted nickel(II) tetraphenylporphyrins. Russ J Org Chem 53, 1094–1098 (2017). https://doi.org/10.1134/S1070428017070235

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  • DOI: https://doi.org/10.1134/S1070428017070235

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