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Study of acid-base properties of weak electrolytes by conductometric titration

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Abstract

Processing of nonlinear conductometric titration curves of aqueous solutions of weak electrolytes (∼10−4 mol/L) has been developed, accounting for dissociation of water and describing the established protolytic equilibriums involving dissolved carbon dioxide. By the nonlinear regression analysis dissociation constants of phenol, aniline, and other weak acids and bases were obtained.

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Authors and Affiliations

  1. Novbytkhim, ul. Zheleznodorozhnaya 45, Gatchina, 188300, Russia

    A. V. Selitrenikov & Yu. E. Zevatskii

  2. St. Petersburg State University of Technology and Design, St. Petersburg, Russia

    Yu. E. Zevatskii

  3. St. Petersburg State Electrotechnical University, St. Petersburg, Russia

    Yu. E. Zevatskii

Authors
  1. A. V. Selitrenikov
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  2. Yu. E. Zevatskii
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Correspondence to A. V. Selitrenikov.

Additional information

Original Russian Text © A.V. Selitrenikov, Yu.E. Zevatskii, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 1, pp. 9–16.

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Selitrenikov, A.V., Zevatskii, Y.E. Study of acid-base properties of weak electrolytes by conductometric titration. Russ J Gen Chem 85, 7–13 (2015). https://doi.org/10.1134/S1070363215010028

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  • DOI: https://doi.org/10.1134/S1070363215010028

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