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Structure and intramolecular flexibility of N-(thio)phosphoryl(thio)amides: XVIII. Structure of N-phenyl,N′-(diisopropoxythiophosphoryl)thiourea

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Abstract

Structure and intramolecular transformations of N-phenyl,N′-(diisopropoxythiophosphoryl)thiourea has been studied by NMR spectroscopy and the AM1 quantum-chemical simulation. It has been shown that several forms, including two amide forms (EZ and ZE) and two prototropic forms, coexist in a dynamic equilibrium.

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Authors and Affiliations

  1. Kazan State University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    F. Kh. Karataeva, A. A. Baltaev & F. D. Sokolov

Authors
  1. F. Kh. Karataeva
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  2. A. A. Baltaev
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  3. F. D. Sokolov
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Corresponding author

Correspondence to F. Kh. Karataeva.

Additional information

Original Russian Text © F.Kh. Karataeva, A.A. Baltaev, F.D. Sokolov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 11, pp. 1845–1849.

For communication XVII, see [1].

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Karataeva, F.K., Baltaev, A.A. & Sokolov, F.D. Structure and intramolecular flexibility of N-(thio)phosphoryl(thio)amides: XVIII. Structure of N-phenyl,N′-(diisopropoxythiophosphoryl)thiourea. Russ J Gen Chem 84, 2142–2146 (2014). https://doi.org/10.1134/S1070363214110176

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  • DOI: https://doi.org/10.1134/S1070363214110176

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