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Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework

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Abstract

A new MOF of [Co(HCOO)2] · 0.33DMF (I) was prepared and characterized by IR, powder X-ray diffraction, and single-crystal X-ray diffraction (CIF file CCDC no. 1571166). Complex I exhibits a diamond framework based on Co-centered CoCo4 tetrahedral nodes, in which all metal ions have octahedral coordination geometry and all HCOO groups link the metal ions in syn-syn/anti modes. The magnetic property shows a main antiferromagnetic interaction and the ferromagnetic phase transition below 2 K. Furthermore, the photocatalytic properties of I for degradation of the methyl violet and Rhodamine B have been explored.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xian, P.R. China

    F. M. Wang

  2. Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy, Guangdong Medical University, Dongguan, 523808, P.R. China

    B. H. Li, Z. D. Luo, J. Q. Liu & A. Q. Ma

  3. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata, 990-8560, Japan

    H. Sakiyama

Authors
  1. F. M. Wang
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  2. B. H. Li
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  3. Z. D. Luo
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  4. J. Q. Liu
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  5. H. Sakiyama
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  6. A. Q. Ma
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Correspondence to A. Q. Ma.

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Wang, F.M., Li, B.H., Luo, Z.D. et al. Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework. Russ J Coord Chem 44, 415–420 (2018). https://doi.org/10.1134/S1070328418070011

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  • DOI: https://doi.org/10.1134/S1070328418070011

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