Skip to main content
SpringerLink
Log in

New preparation method of chlorotriphenylantimony aryloxides Ph3SbCl(OAr)

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The reaction of bis(2,6-dichlorophenoxo)triphenylantimony with triphenylantimony dichloride gave chloro(2,6-dichlorophenoxo)triphenylantimony Ph3SbCl(OC6H3Cl2-2,6) (I). 2,6-Dichlorophenoxotetraphenylantimony Ph4Sb(OC6H3Cl2-2,6) (II) was prepared from pentaphenylantimony and bis(2,6- dichlorophenoxo)triphenylantimony. According to X-ray diffraction data, the antimony atoms in I and II have a distorted trigonal-bipyramidal coordination with the following axial: OSbCl, 179.59(5)° (I); CSbO, 178.20(14)° (II); the equatorial angles are 115.72(9)°–124.87(10)° (I) and 111.43(18)°–123.18(19)° (II); the equatorial bond lengths are Sb–C, 2.099(3)–2.111(2) Å (I), 2.111(4)–2.122(5) Å (II); and the axial bond lengths are Sb–Cl, 2.4740(7) Å; Sb–O, 2.0802(16) Å (I); Sb–O, 2.237(3) Å; and Sb–C, 2.167(4) Å (II) (CIF files CCDC no. 998625 for I and no. 1010553 for II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chauhan, A.K.S., Mishra, Sh., and Srivastava, R.C., Main Group Met. Chem., 2000, vol. 23, no. 5, p. 277.

    Article  CAS  Google Scholar 

  2. Sharutin, V.V. and Senchurin, V.S., Imennye reaktsii v khimii elementoorganicheskikh soedinenii (Name Reactions in the Organometallic Chemistry), Chelyabinsk: YuUrGU, 2011.

    Google Scholar 

  3. Sharutin, V.V., Senchurin, V.S., Sharutina, O.K., et al., Russ. J. Gen. Chem., 1996, vol. 66, no. 10, p. 1710.

    Google Scholar 

  4. Sharutin, V.V., Sharutina, O.K., Osipov, P.E., and Subacheva, O.V., Russ. J. Gen. Chem., 2001, vol. 71, no. 6, p. 983.

    Article  CAS  Google Scholar 

  5. Sharutin, V.V., Sharutina, O.K., Pakusina, A.P., and Bel’skii, V.K., Russ. J. Gen. Chem., 1997, vol. 67, no. 9, p. 1443.

    CAS  Google Scholar 

  6. Sharutin, V.V., Sharutina, O.K., Panova, L.P., and Bel’skii, V.K., Russ. J. Gen. Chem., 1997, vol. 67, no. 9, p. 1438.

    CAS  Google Scholar 

  7. Sharutin, V.V., Sharutina, O.K., Egorova, I.V., and Panova, L.P., Russ. J. Gen. Chem., 1998, vol. 68, no. 2, p. 318.

    CAS  Google Scholar 

  8. Sharutin, V.V., Sharutina, O.K., Nasonova, N.V., et al., Russ. J. Gen. Chem., 2001, vol. 71, no. 8, p. 1238.

    Article  CAS  Google Scholar 

  9. Long, G.G., Moreland, C.G., Doak, G.O., and Miller, M., Inorg. Chem., 1966, vol. 5, no. 8, p. 1358.

    Article  CAS  Google Scholar 

  10. Chaudhari, K.R., Jain, V.K., Sagoria, V.S., and Tiekink, E.R.T., J. Organomet. Chem., 2007, vol. 692, no. 22, p. 4928.

    Article  CAS  Google Scholar 

  11. Gupta, A., Sharma, R.K., Bohra, R., et al., J. Organomet. Chem., 2002, vol. 645, nos. 1–2, p. 118.

    Article  CAS  Google Scholar 

  12. Gupta, A., Sharma, R.K., Bohra, R., et al., Polyhedron, 2002, vol. 21, no. 23, p. 2387.

    Article  CAS  Google Scholar 

  13. Sharutin, V.V., Sharutina, O.K., and Molokova, O.V., Butlerov. Soobshch., 2011, vol. 28, p. 45.

    Google Scholar 

  14. SMART and SAINT-Plus.Versions 5.0. Data Collection and Processing Software for the SMART System, Madison: Bruker AXS Inc., 1998.

  15. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Madison: Bruker AXS Inc., 1998.

  16. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  17. Sharutin, V.V., Sharutina, O.K., and Matveeva, K.V., Butlerov. Soobshch., 2014, vol. 39, no. 8, p. 94.

    Google Scholar 

  18. Doak, G.O., Long, G.G., and Freedman, L.D., J. Organomet. Chem., 1965, vol. 4, no. 1, p. 82.

    Article  CAS  Google Scholar 

  19. MacDonald, D.J., Jennings, M.C., and Preuss, K.E., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2010, vol. 66, p. m137.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

Authors
  1. V. V. Sharutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. K. Sharutina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Senchurin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Sharutin.

Additional information

Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 1, pp. 34–38.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharutin, V.V., Sharutina, O.K. & Senchurin, V.S. New preparation method of chlorotriphenylantimony aryloxides Ph3SbCl(OAr). Russ J Coord Chem 42, 32–36 (2016). https://doi.org/10.1134/S1070328415120076

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328415120076

Keywords

Search

Navigation