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Extraction of REE(III), U(VI), and Th(IV) from Perchloric Acid Solutions with 2,6-Bis(diphenylphosphorylmethyl)pyridine N-Oxide

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Radiochemistry Aims and scope

Abstract

The extraction of microamounts of REE(III), U(VI), and Th(IV) from HClO4 solutions with solutions of 2,6-bis(diphenylphosphorylmethyl) pyridine N-oxide (I) in 1,2-dichloroethane was studied depending on the HClO4 concentration in the equilibrium aqueous phase. The stoichiometry of the extracted complexes was determined. It was shown that compound I extracts REE(III), U(VI), and Th(IV) from dilute HClO4 solutions with much higher efficiency than from HNO3 solutions. With an increase in the concentration of acids, the magnitude of the “perchlorate” effect upon extraction of REE(III) and U(VI) decreases, and Th(IV) is extracted by compound I from HClO4 solutions with lower efficiency than from HNO3 solutions.

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Funding

The study was carried out within the framework of the State Project 2019 of ISSP RAS, IMT RAS, IPAC RAS, and IPCE RAS under partial support by the Russian Foundation for Basic Research (project 18-29-24069).

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. N. Turanov

  2. Institute for Problems of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. K. Karandashev & V. A. Khvostikov

  3. Institute of Physiologically Active Compounds, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. E. Baulin

  4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. Yu. Tsivadze

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. V. A. Khvostikov
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  4. V. E. Baulin
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  5. A. Yu. Tsivadze
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Correspondence to A. N. Turanov.

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Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 1, pp. 30–36, December, 2020 https://doi.org/10.31857/S0033831121010056

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Turanov, A.N., Karandashev, V.K., Khvostikov, V.A. et al. Extraction of REE(III), U(VI), and Th(IV) from Perchloric Acid Solutions with 2,6-Bis(diphenylphosphorylmethyl)pyridine N-Oxide. Radiochemistry 63, 28–34 (2021). https://doi.org/10.1134/S1066362221010057

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