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Extraction of REE(III), U(VI), and Th(IV) from Perchlorate Solutions with Tetraphenyl(o-oxyphenylenemethylene)diphosphine Dioxide

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Abstract

The extraction of microamounts of REE(III), U(VI), and Th(IV) from perchlorate solutions with solutions of tetraphenyl(o-oxyphenylenemethylene)diphosphine dioxide (I) in 1,2-dichloroethane was studied. The stoichiometry of the extractable complexes was determined, and the influence of the aqueous phase composition on the efficiency and selectivity of the extraction of U(VI), Th(IV), and REE(III) into the organic phase was analyzed. In going from nitric to perchloric acid solutions, the efficiency of the extraction of REE(III), U(VI), and Th(IV) with solutions of I considerably decreases, whereas the selectivity of the U(VI)/REE(III) separation increases.

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, ul. Akademika Osip’yana 2, Chernogolovka, Moscow oblast, 142432, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High-Purity Materials, Russian Academy of Sciences, ul. Akademika Osip’yana 6, Chernogolovka, Moscow oblast, 142432, Russia

    V. K. Karandashev

  3. National University of Science and Technology MISIS, Leninskii pr. 4, Moscow, 119991, Russia

    V. K. Karandashev

  4. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432, Russia

    V. E. Baulin

  5. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow, 119991, Russia

    V. E. Baulin & D. V. Baulin

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  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. V. E. Baulin
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  4. D. V. Baulin
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Correspondence to A. N. Turanov.

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Turanov, A.N., Karandashev, V.K., Baulin, V.E. et al. Extraction of REE(III), U(VI), and Th(IV) from Perchlorate Solutions with Tetraphenyl(o-oxyphenylenemethylene)diphosphine Dioxide. Radiochemistry 61, 156–161 (2019). https://doi.org/10.1134/S1066362219020048

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  • DOI: https://doi.org/10.1134/S1066362219020048

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