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Synthesis, crystal structure, and properties of new actinide(VI) arsenates (H3O)[(AnO2)(AsO4)]·3H2O (An = U, Np, Pu)

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Abstract

Previously unknown arsenates of hexavalent U, Np, and Pu, (H3O)[(UO2)(AsO4)]·3H2O (I), (H3O)· [(NpO2)(AsO4)]·3H2O (II), and (H3O)[(PuO2)(AsO4)]·3H2O (III), were synthesized under hydrothermal conditions. The crystal structure of the compounds was determined, and their absorption spectra were measured. The compounds crystallize in tetragonal space group P4/nmm.

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References

  1. Frondel, C., Systematic Mineralogy of Uranium and Thorium, USGovernment, 1958.

  2. Barinova, A.V., Rastsvetaeva, R.K., Pushcharovskii, D.Yu., and Suleimanov, E.V., Abstracts of Papers, III Natsional’naya kristallokhimicheskaya konferentsiya (III National Crystal-Chemical Conf.), Chernogolovka, 2003.

  3. Agilent, Yarnton (England): Agilent Technologies Ltd., 2014.

  4. Clark, R.C. and Reid, J.S., Acta Crystallogr., Sect. A, 1995, vol. 51, no. 6, pp. 887–897.

    Article  Google Scholar 

  5. Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, no. 1, pp. 3–8.

    Article  Google Scholar 

  6. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, no. 2, pp. 339–341.

    Article  CAS  Google Scholar 

  7. Nardelli, M., J. Appl. Crystallogr., 1999, vol. 32, no. 3, pp. 563–571.

    Article  CAS  Google Scholar 

  8. Weigel, F. and Hoffmann, G., J. Less-Common Met., 1976, vol. 44, pp. 125–132.

    Article  CAS  Google Scholar 

  9. Fischer, R., Werner, G.-D., Lehmann, T., et al., J. Less-Common Met., 1981, vol. 80, no. 1, pp. 121–132.

    Article  CAS  Google Scholar 

  10. Morosin, B., Acta Crystallogr., Sect. B, 1978, vol. 34, no. 12, pp. 3732–3734.

    Article  Google Scholar 

  11. Beintema, J., Recl. Trav. Chim. Pays-Bas, 1938, vol. 57, pp. 155–175.

    Article  CAS  Google Scholar 

  12. Ross, M. and Evans, H.I., Am. Mineral., 1965, vol. 50, pp. 1–12.

    CAS  Google Scholar 

  13. Locock, A.J. and Burns, P.C., J. Solid State Chem., 2003, vol. 176, no. 1, pp. 18–26.

    Article  CAS  Google Scholar 

  14. Locock, A.J. and Burns, P.C., Can. Mineral., 2005, vol. 43, pp. 721–733.

    Article  CAS  Google Scholar 

  15. Shchipanova, O.V., Belova, L.N., Pribytkov, P.V., and Katargina, A.P., Dokl. Akad. Nauk SSSR, 1971, vol. 197, no. 1, pp. 178–180.

    CAS  Google Scholar 

  16. Locock, A.J. and Burns, P.C., Can. Mineral., 2003, vol. 41, no. 2, pp. 489–502.

    Article  CAS  Google Scholar 

  17. Fitch, A.N., Bernard, L., Howe, A.T., et al., Acta Crystallogr., Sect. C, 1983, vol. 39, no. 2, pp. 159–162.

    Article  Google Scholar 

  18. Stoyanov, E.S., Kee-Chan Kim. and Reed, Ch.A., J. Am. Chem. Soc., 2006, vol. 128, pp. 1948–1958.

    Article  CAS  Google Scholar 

  19. Schuster, P., Zungel, G., and Sandorfy, C., The Hydrogen Bond, Amsterdam: North-Holland, 1976, vol. II.

    Google Scholar 

  20. Ruipérez, F., Danilo, C., Réal, F., et al., J. Phys. Chem. A, 2009, vol. 113, pp. 1420–1428.

    Article  Google Scholar 

  21. Servaes, K., Hennig, H., van Deun, R., and Görller-Walrand, C., Inorg. Chem., 2005, vol. 44, pp. 7705–7707.

    Article  CAS  Google Scholar 

  22. Silva, R.J. and Nitsche, H., Radiochim. Acta, 1995, vols. 70–71, pp. 377–396.

    Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, korp. 4, Moscow, 119071, Russia

    A. G. Ivanova, N. A. Budantseva & A. M. Fedoseev

  2. Federal Research Center for Crystallography and Photonics, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    A. G. Ivanova

Authors
  1. A. G. Ivanova
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  2. N. A. Budantseva
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  3. A. M. Fedoseev
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Correspondence to N. A. Budantseva.

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Original Russian Text © A.G. Ivanova, N.A. Budantseva, A.M. Fedoseev, 2017, published in Radiokhimiya, 2017, Vol. 59, No. 2, pp. 106–109.

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Ivanova, A.G., Budantseva, N.A. & Fedoseev, A.M. Synthesis, crystal structure, and properties of new actinide(VI) arsenates (H3O)[(AnO2)(AsO4)]·3H2O (An = U, Np, Pu). Radiochemistry 59, 119–123 (2017). https://doi.org/10.1134/S1066362217020035

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  • DOI: https://doi.org/10.1134/S1066362217020035

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