Abstract
The solubility of PuF3 and UF4 added jointly into a melt of the molar composition 46.5LiF–11.5NaF–42KF was studied in the temperature range 823–1073 K. Anhydrous PuF3 and UF4 were synthesized. The isothermal saturation method was used in studying the dissolution of pressed PuF3 and UF4 pellets in the melt in an inert (argon) atmosphere. The temperature dependences of the solubilities of jointly added PuF3 and UF4 in the LiF–NaF–KF melt of the chosen composition were determined. The solubilities of PuF3 and UF4 added into the LiF–NaF–KF melt jointly are lower than the solubilities of the same fluorides added separately.
Similar content being viewed by others
References
Seregin, M.B., Parshin, A.P., Kuznetsov, A.Yu., et al., Radiochemistry, 2011, vol. 53, no. 1, pp. 69–72.
Seregin, M.B., Parshin, A.P., Kuznetsov, A.Yu., et al., Radiochemistry, 2011. vol. 53, no. 5. pp. 491–493.
Ponomarev, L.I., Seregin, M.B., Mikhalichenko, A.A., et al., At. Energy, 2012, vol. 112, no. 6, pp. 341–346.
Lizin, A.A., Tomilin, S.V., Gnevashov, O.E., et al., At. Energy, 2013, vol. 115, no. 1, pp. 11–17.
Lizin, A.A., Tomilin, S.V., Gnevashov, O.E., et al., At. Energy, 2013, vol. 115, no. 1, pp. 22–25.
Lizin, A.A., Tomilin, S.V., Elesin, A.A., et al., A study of the joint solubility of cerium and plutonium trifluorides in the salt systems 78LiF–7ThF4–15UF4 an. 72.5LiF–7ThF4–20.5UF4, Report on Main Research Works in 2013, Dimitrovgrad: Research Inst. of Atomic Reactors, 2014. pp. 138–139.
Mushnikov, P.N., Smolenskii, V.V., Novoselova, A.V., and Lizin, A.A., Ftoridnye tekhnologii v atomnoi promyshlennosti. Gromovskie chteniya 2014: Materialy Vserossiiskoi nauchno-prakticheskoi konferentsii, pri urochennoi k 105-letiyu so dnya rozhdeniya B.V. Gromova (Fluoride Technologies in Atomic Industry. Gromov Readings 2014: Proc. All-Russia Scientific and Practical Conf. Dedicated to 105th B.V. Gromov Birthday Anniversary), Gromov, O.B., Ed., Tomsk, Oct. 1–3, 2014. Tomsk: Tomskii Politekh. Univ., 2014. pp. 50–51.
Ignatiev, V.V., Feynberg, O.S., Zagnitko, A.V., et al., At. Energy, 2012, vol. 112, no. 3, pp. 157–165.
Ignatiev, V., Feynberg, O., Lizin, A., et al., Ann. Nucl. Energy, 2014, vol. 64, pp. 408–420.
Ignatiev, V.V., Merzlyakov, A.V., Subbotin, V.G., et al., At. Energy, 2006, vol. 101, no. 5, pp. 822–829.
Naumov, V., Experimental and computational studies for the justification of creating molten salt fast reactors, United States–Russian Federation Molten Salt Reactor (MSR) and Fluoride Salt-Cooled High-Temperature Reactor (FHR) Technical Exchange Meet., Oak Ridge, Tennessee (USA): Oak Ridge National Laboratory, November 19–20, 2013.
Volozhin, M.V., Zakirov, R.Ya., Mushnikov, P.N., et al., At. Energy, 2013, vol. 115, no. 1, pp. 18–21.
Degtyarev, A.M. and Ponomarev, L.I., At. Energy, 2012, vol. 112, no. 6, pp. 451–453.
Gulevich, A., Kalugin, A., Ponomarev, L., et al., Prog. Nucl. Energy, 2008. vol. 50, March–August, p. 358.
Velikhov, E.P., Koval’chuk, M.V., Azizov, E.A., et al., At. Energy, 2013, vol. 114, no. 3, pp. 197–202.
Powder Diffraction File, Swarthmore, Pennsylvania (USA): Int. Center for Diffraction Data, 1999.
Lizin, A.A., Tomilin, S.V., Ignat’ev, V.V., et al., Radiochemistry, 2015, vol. 57, no. 1, pp. 36–42.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Original Russian Text © A.A. Lizin, S.V. Tomilin, V.S. Naumov, V.V. Ignat’ev, N.Yu. Nezgovorov, A.Yu. Baranov, 2015, published in Radiokhimiya, 2015, Vol. 57, No. 5, pp. 425–429.
Rights and permissions
About this article
Cite this article
Lizin, A.A., Tomilin, S.V., Naumov, V.S. et al. Joint solubility of PuF3 and UF4 in a melt of lithium, sodium, and potassium fluorides. Radiochemistry 57, 498–503 (2015). https://doi.org/10.1134/S1066362215050082
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362215050082