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Structural Characteristics and Processability of Sphalerite in Lead-Zinc Ore of the Gorevka Deposit

  • Mineral Dressing
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Abstract

The theoretical and experimental substantiation of the behavior of ferrous sphalerite in magnetic separation is given in terms of the Gorevka deposit ore. In sphalerite of this deposit, the content of isomorphous iron ranges as 4–9%. The Móssbauer spectroscopy showed the singlet and two doublet lines of iron, demonstrating separate arrays of iron atoms in sphalerite lattice, with formation of Fe-Fe pairs and clusters of three or more iron atoms. It is found that distribution of iron in sphalerite into three forms coincides for magnetic and nonmagnetic products of zinc concentrate separation. It is determined that magnetic separation undivides sphalerite grains by the isomorphous iron content but is governed by the genetic features of the deposit formation—association of sphalerite with magnetic minerals (pyrrhotine and siderite) and the absence of such associations in galena.

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References

  1. Izoitko, V.M., Tekhnologicheskaya mineralogiya i otsenka rud (Engineering Mineralogy and Ore Evaluation), Saint-Petersburg: Nauka, 1997.

    Google Scholar 

  2. Chupenova, R.T., Bykov, R.A., and Seksenova, N.K., Osobennosti izvlecheniya tsinka pri flotatsii polimetallicheskoi rudy Ridder-Sokol ’nogo mestorozhdeniya (Specificity of Zinc Extraction in Flotation of Complex Ore from the Ridder-Sokol deposit). Available at: http://www.rusnauka.com/pdf/239514.pdf

  3. Jian-Tao Lang, Si-Qing Liu, Xu Dong, and Yi Pei, Current Situation on Flotation of Cu-Pb-Zn Sulfide Ore, J. Advances in Engineering Research, 2018, vol. 120, pp. 1972–1976.

    Google Scholar 

  4. Jiang, C.L., Qu, S.S., and Wang, L.Z., Study on the Occurrence of Cu-Pb-Zn-Ag in a Polymetallic Ore in Inner Mongolia and the Mineralogical Factors Affecting Mineral Processing, J. Metallurgical Engineering, 2015, pp. 41–44.

    Google Scholar 

  5. Abramov, A.A. Flotatsionnye metody obogashcheniya (Flotation Methods), Moscow: MGGU, 2008.

    Google Scholar 

  6. Kondratéeva, A.A., Bragin, V.I., Burdakova, E.A., Baksheeva, I.I., and Glumova, A.A., Improvement of Complex Ore Processing Technology by Using Combinations f Collecting Agents, GIAB, 2013, no. 8, pp. 34–39.

    Google Scholar 

  7. Pomianowski, A., Szczypa, J., Poling, G.W., and Leja, J., Influence of Iron Content in Sphalerite-Marmatite on Copper Ion Activation in Flotation, Proc. of the 11th Min. Proc. Congr., Cagliari, 1975, pp. 639–653.

    Google Scholar 

  8. Mukherjee, A.D. and Sen, P.K., Floatability of Sphalerite in Relation to Its Iron Content, J. Mines, Metals and Fuels, 1976, vol. 24, no. 10, pp. 327–330.

    Google Scholar 

  9. Gigowski, B., Vogg, A., Wierer, K., and Dobias, B., Effect of Fe Lattice Ions on Adsorption, Electrokinetic, Calorimetric and Flotation Properties of Sphalerite, Int. J. Min. Proc, 1991, vol. 33, pp. 103–120.

    Article  Google Scholar 

  10. Boulton, A., Fornasier, D., and Ralston, J., Effect of Iron Content in Sphalerite on Flotation, J. Min. Eng., 2005, vol. 18, pp. 1120–1122.

    Article  Google Scholar 

  11. Bulatovic, S.M., Handbook of Flotation Reagents, Elsevier Sci., 2007.

    Google Scholar 

  12. Gunter, C.G., Electro-Magnetic Ore Separation, Hill Publishing Company, New York, 1909.

    Google Scholar 

  13. Johansson, B., Purification of Complex Lead Concentrate by High Intensity Magnetic Separation, Proc. Conf. onMin. Proc, Feb., Lutea, 1990, pp. 105–115.

    Google Scholar 

  14. Jirestig, J. and Forssberg, E., Magnetic Characterization of Sulfide Ores: Examples from Sweden, J. Magnetic and Electrical Separation, 1993, vol. 4, pp. 31–45.

    Article  Google Scholar 

  15. Plotnikova, A.A. and Bragin, V.I., Upgrading Lead Concentrates by Magnetic Methods, Tsv. Metally, 2018, no. 12, pp. 21–26.

    Google Scholar 

  16. Korolev, N.A., Venger, M.K., Korolev, I.A., and Voznaya, A.A., Engineering Mineralogy Applications in Ore Dressing Circuits, Vestn. SibGIU, 2018, no. 1 (23), pp. 27–31.

    Google Scholar 

  17. Ozhogina, E.G., Engineering Mineralogy of Manganese Ore in Siberia, Russian Workshop on Engineering Mineralogy: Transactions, Petrozavodsk: Karel. NTS RAN, 2009, pp. 28–32.

    Google Scholar 

  18. Bulatov, F.M., Typomorphism and Specific Crystallochemistry of Stratified Silicates by the Mössbauer Spectroscopy, Georesursy, 2012, no. 6 (48), pp. 3–8.

    Google Scholar 

  19. Xing-Wu Liu, Shu Zhao, Yu Meng, Qing Peng, Albert K. Dearden, Chun-Fang Huo, Yong Yang, Yong-Wang Li, and Xiao-Dong Wen, Mossbauer Spectroscopy of Iron Carbides: From Prediction to Experimental Confirmation, Scientific Reports, 2016, vol. 6, pp. 1–10.

    Article  Google Scholar 

  20. Pearce, I.C., Pattrick, R.A.D., and Vaughan, D.J., Electrical and Magnetic Properties of Sulfides, Reviews in Mineralogy and Geochemistry, 2006, vol. 61, pp. 127–180.

    Article  Google Scholar 

  21. Bogdanov, O.S., Spravochnik po obogashcheniyu rud (Ore Dressing Manual), Moscow: Nedra, 1983, vol. 2.

  22. Zussman, J., Deer, W., and Howie, R.A., Introduction to the Rock-Forming Minerals, Mineralogical Society of Great Britain and Ireland, 3rd Edition, 2013.

    Google Scholar 

  23. Ramdohr, P., The Ore Minerals and Their Intergrowths, Pergamon, 1969.

    Google Scholar 

  24. Barton, P.B. Jr. and Toulmin, P., Phase Relations Involving Sphalerite in the Fe-Zn-S System, J. Economic Geol., 1966, vol. 61, pp. 815–849.

    Article  Google Scholar 

  25. Barnes, H.L., Geochemistry of Hydrothermal Ore Deposits, 3rd Edition, Wiley, 1997.

    Google Scholar 

  26. Scott, S.D. and Kissin, S.A., Sphalerite Composition in the Fe-Zn-S System below 300°G, J. Economic Geol, 1973, vol. 68, pp. 475–479.

    Article  Google Scholar 

  27. Chareev, D.A., Osadchii, V.O., Shiryaev, A.A., Nekrasov, A.N., Koshelev, A.V., and Osadchii, E.G., Single Crystal Fe-Bearing Sphalerite: Synthesis, Lattice Parameter, Thermal Expansion Coefficient and Microhardness, J. Phys. and Chem. of Min., 2017, pp. 287–296.

    Google Scholar 

  28. Benedetto, F. Di, Andreozzi, G.B., Bernardini, G.P., Borgheresi, M., Caneschi, A., Cipriani, C., Gatteschi, D., and Romanelli, M., Short-Range Order of Fe2+ In Sphalerite by Fe Mössbauer Spectroscopy and Magnetic Susceptibility, J. Phys. andChem. of Min., 2005, vol. 32, pp. 339–348.

    Article  Google Scholar 

  29. Wright, K. and Gale, J.D., A First Principles Study of the Distribution of Iron In Sphalerite, Geohimica et Cosmochimica Acta, 2010, vol. 74, pp. 3514–3520.

    Article  Google Scholar 

  30. Lepetit, P., Bente, K., Doering, T., and Luckhaus, S., Crystal Chemistry of Fe-Containing Sphalerites, J. Phys. andChem. of Min., 2003, vol. 30, no. 4, pp. 185–191.

    Article  Google Scholar 

  31. Burdakova, E.A. and Kondrat’ev, S.A., Contribution of Physisorption of Collectors to Flotation Aggregate Formation in Terms of Sulfide Ores, Plaksin ’s Lectures-2017: Recent Problems of Integrated Processing of Rebellious Ore and Mining Waste, Krasnoyarsk: SFU, 2017, pp. 196–199.

    Google Scholar 

  32. Zielinski, P.A., Larson, K.A., and Stradling, A.W., Preferential Deportment at Low-Iron Sphalerite to Lead Concentrates, J. Min. Eng., 2000, vol. 13, pp. 357–363.

    Article  Google Scholar 

  33. Kondoro, J.W.A., Mössbauer Study of Vacancies in Natural Pyrrhotite, J. Alloys and Compounds, 1999, vol. 289, pp. 36–41.

    Article  Google Scholar 

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Correspondence to A. A. Plotnikova.

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Russian Text © The Author(s), 2019, published in Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, 2019, No. 6, pp. 152–164.

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Plotnikova, A.A., Bragin, V.I. & Knyazev, Y.V. Structural Characteristics and Processability of Sphalerite in Lead-Zinc Ore of the Gorevka Deposit. J Min Sci 55, 995–1006 (2019). https://doi.org/10.1134/S1062739119066381

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  • DOI: https://doi.org/10.1134/S1062739119066381

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