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Use of composite films based on poly(3,4-ethylenedioxythiophene) with inclusions of palladium nanoparticles in voltammetric sensors for hydrogen peroxide

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Abstract

Possibilities of using new electrode materials PEDOT/Pd and PEDOT:PSS/Pd (where PEDOT is poly(3,4-ethylenedioxythiophene) and PEDOT:PSS is poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate) prepared by the chemical deposition of ultradispersed Pd particles into a polymer matrix as sensor materials for the determination of H2O2 are considered. The structure of films is characterized by electron microscopy and energy dispersive X-ray fluorescence analysis. The voltammetric responses of PEDOT/Pd and PEDOT:PSS/Pd films in solutions containing H2O2 are studied. The conditions of the voltammetric determination of H2O2 on modified metal–polymer electrodes are optimized.

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Authors and Affiliations

  1. Institute of Applied Chemistry and Ecology, St. Petersburg State University of Technology and Design, Bol’shaya Morskaya ul. 18, St. Petersburg, 191186, Russia

    A. M. Smolin & N. P. Novoselov

  2. Institute of Chemistry, St. Petersburg State University, Petrodvorets, niversitetskii pr. 26, St. Petersburg, 198504, Russia

    T. A. Babkova, S. N. Eliseeva & V. V. Kondrat’ev

Authors
  1. A. M. Smolin
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  2. N. P. Novoselov
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  3. T. A. Babkova
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  4. S. N. Eliseeva
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  5. V. V. Kondrat’ev
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Correspondence to A. M. Smolin.

Additional information

Original Russian Text © A.M. Smolin, N.P. Novoselov, T.A. Babkova, S.N. Eliseeva, V.V. Kondrat’ev, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 8, pp. 846–853.

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Smolin, A.M., Novoselov, N.P., Babkova, T.A. et al. Use of composite films based on poly(3,4-ethylenedioxythiophene) with inclusions of palladium nanoparticles in voltammetric sensors for hydrogen peroxide. J Anal Chem 70, 967–973 (2015). https://doi.org/10.1134/S1061934815080171

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  • DOI: https://doi.org/10.1134/S1061934815080171

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