Skip to main content
Log in

Electrochemical properties of composite materials based on poly-3,4-Ethylenedioxythiophene with nickel oxide inclusions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The electrochemical behavior of PEDOT/NiO composite films obtained by electrochemical deposition of nickel into poly-3,4-ethylenedioxythiophene (PEDOT) films followed by oxidation in weakly alkaline solutions was studied by cyclic voltammetry. When a complex polymer composite with two sequentially deposited PEDOT/NiO layers was prepared, the charge almost doubled. The morphology of the obtained composite films was studied by scanning electron microscopy (SEM); the element composition was analyzed by local energy dispersion (EDX) analysis. The nickel distribution over the surface was mapped for the PEDOT/Ni and PEDOT/NiO composite films. The specific capacity of the obtained materials and their dependence on the potential scan rate were determined by cyclic voltammetry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yu, G., Xie, X., Pan, L., Boo, Z., and Cui, Y., Nano Energy, 2013, vol. 2, p. 213.

    Article  CAS  Google Scholar 

  2. Holze, R. and Wu, Y.P., Electrochim. Acta, 2014, vol. 122, p. 93.

    Article  CAS  Google Scholar 

  3. Lu, A.H. and Schuth, F., Adv. Mater., 2006, vol. 18, p. 1793.

    Article  CAS  Google Scholar 

  4. Xia, X.H., Tu, J.P., Zhang, J., Huang, X.H., Wang, X.L., Zhang, W.K., and Huang, H., Electrochem. Commun., 2009, vol. 11, p. 702.

    Article  CAS  Google Scholar 

  5. Wang, D.-W., Li, F., and Cheng, H.-M., J. Power Sources, 2008, vol. 185, p. 1563.

    Article  CAS  Google Scholar 

  6. Machado, S.A. and Avaca, L.A., Electrochim. Acta, 1994, vol. 39, no. 10, p. 1385.

    Article  CAS  Google Scholar 

  7. Sokol’skii, D.V., Zabotin, P.I., and Druz’, S.V., Elektrokhimiya, 1979, vol. 5, p. 81.

    Google Scholar 

  8. Pshenichnikov, A.G., Kudryavtseva, Z.I., and Burkal’tseva, L.A., Elektrokhimiya, 1995, vol. 31, p. 1065.

    Google Scholar 

  9. Korovin, N.V., Kumenko, M.V., and Kozlova, N.I., Elektrokhimiya, 1987, vol. 23, p. 408.

    CAS  Google Scholar 

  10. Xu, M.W., Bao, S.J. and Ki, H.L., J. Solid State Electrochem., 2007, vol. 11, p. 372.

    Article  CAS  Google Scholar 

  11. Fang, D.-L., Chen, Z.D., Liu, X., Wu, Z.F., and Zheng, Ch.., Electrochim. Acta, 2012, vol. 81, p. 321.

    Article  CAS  Google Scholar 

  12. Tolstopyatova, E.G., Pogulyaichenko, N.A., Eliseeva, S.N., and Kondratiev, V.V., Russ. J. Electrochem., 2009, vol. 45, p. 252.

    Article  CAS  Google Scholar 

  13. Lainer, V.I. Zashchitnye pokrytiya metallov (Protective Coatings of Metals), Moscow: Metallurgiya, 1974, p. 361.

    Google Scholar 

  14. Tsakova, V., J. Solid State Electrochem., 2008, vol. 12, p. 1421.

    Article  CAS  Google Scholar 

  15. Podlovchenko, B.I. and Andreev, V.N., Usp. Khim., 2002, vol. 71, p. 950.

    Article  Google Scholar 

  16. Eliseeva, S.N., Ubyivovk, E.V., Bondarenko, A.S., Vyvenko, O.F., and Kondratiev, V.V., Russ. J. Gen. Chem., 2010, vol. 80, p. 1143.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Kondratiev.

Additional information

Original Russian Text © A.O. Nizhegorodova, R.V. Apraksin, V.V. Kondratiev, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 10, pp. 1030–1038.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nizhegorodova, A.O., Apraksin, R.V. & Kondratiev, V.V. Electrochemical properties of composite materials based on poly-3,4-Ethylenedioxythiophene with nickel oxide inclusions. Russ J Electrochem 51, 908–915 (2015). https://doi.org/10.1134/S1023193515100092

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193515100092

Keywords

Navigation