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Reduced graphene oxide in the construction of solid-state bromide-selective electrode

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Abstract

To improve the electrochemical performance of solid-state printed electrodes, reduced graphene oxide is used as an intermediate layer (mediator) between the surface layer of a current collector and the ionophore layer. A graphene oxide film was deposited onto the surface of printed electrodes by drop-casting, followed by reduction and electrochemical deposition. An ionic liquid 1,3-dihexadecylimidazolium bromide served as ionophore. The effect of reduced graphene oxide on the characteristics of the ion-selective electrode is studied, and it is shown that the sensors electrochemically modified with reduced graphene oxide have the best performance. These sensors exhibit a stable, well-reproducible response to bromide ions with the slope of the electrode function close to the Nernstian value (−60.7 ± 0.7 mV/dec) and a low detection limit of 3.6 × 10−6 M. The response time for all of the electrodes does not exceed 15 s even in dilute solutions.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119992, Russia

    N. V. Shvedene, A. V. Rzhevskaia, N. M. Anuchin, O. O. Kapitanova, A. N. Baranov & I. V. Pletnev

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  1. N. V. Shvedene
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  2. A. V. Rzhevskaia
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  3. N. M. Anuchin
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  4. O. O. Kapitanova
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  5. A. N. Baranov
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  6. I. V. Pletnev
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Correspondence to N. V. Shvedene.

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Original Russian Text © N.V. Shvedene, A.V. Rzhevskaia, N.M. Anuchin, O.O. Kapitanova, A.N. Baranov, I.V. Pletnev, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 3, pp. 330–335.

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Shvedene, N.V., Rzhevskaia, A.V., Anuchin, N.M. et al. Reduced graphene oxide in the construction of solid-state bromide-selective electrode. J Anal Chem 70, 378–383 (2015). https://doi.org/10.1134/S1061934815030193

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  • DOI: https://doi.org/10.1134/S1061934815030193

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