Abstract
The sufficient amounts of bis(salicylaldehyde) thiocarbohydrazone (STCH) as a lipophilic selective element (3%, w/w), sodium nitrobenzene (NB) as a plasticizer (64%, w/w), tetraphenyl borate (NaTPB) as an anionic additive (3%, w/w), and poly vinyl chloride (PVC) as a polymeric matrix (30%, w/w) was employed to form a PVC membrane of a new Pr3+ ions selective sensor to apply as an indicator electrode in analytical applications. The best electrode response was observed in the slope (19.5 ± 0.7 mV per decade) over a wide concentrations from lower (1.0 × 10−6 mol L–1) to higher (1.0 × 10−2 mol L–1) of Pr3+ ion solution with a detection limit of 8.5 × 10–7 mol L–1. This electrode showed the fast response time about 10 second for praseodymium ion concentration range of 1.0 × 10–6 to 1.0 × 10–2 mol L–1, in the pH range of 2.3–7.9. The matched potential method was applied to study the selectivity of electrode toward Pr3+ ions in comparison with many common cations. The results showed the negligible disturbance of all other cations on the proposed praseodymium(III) electrode. The making sensor has been employed successfully as an indicator electrode in the potentiometric titration of praseodymium(III) solution with EDTA at pH 6.0. Moreover the applicability of the sensor was studied in determination of Pr3+ ion in mixtures of different ions.
Similar content being viewed by others
References
http://www.webelements.com.
Kirk, O.R. and Othmer, F.D., Encyclopedia of Chemical Technology, New York: Wiley, 1982.
Sonke, J.E. and Salters, V.J.M., J. Anal. At. Spectrosc., 2004, vol. 19, p. 235.
Shibata, N., Fudagawa, N., and Kubota, M., Anal. Chem., 1991, vol. 63, p. 636.
Li, B., Sun, Y., and Yin, M.J., Anal. At. Spectrom., 1999, vol. 14, p. 1843.
Liu, Y.M., Spectrosc. Spect. Anal., 2004, vol. 24, p. 1257.
Mazzucotelli, A., DePaz, F., Magi, E., and Frache, R., Anal. Sci., 1992, vol. 8, p. 189.
Meyerhoff, M.E. and Opdyche, M.N., Adv. Clin. Chem., 1986, vol. 25, p. 1.
Moody, G.J., Saad, B.B., and Thomas, J.D.R., Sel. Electrode Rev., 1988, vol. 10, p. 71.
Kimura, K. and Shono, T., Cation Binding by Macrocycles, Inoue, Y. and Gokel, G.W., Eds., New York: Marcel Dekker, 1990.
Greenwood, N.N. and Earnshaw, A., Chemistry of the Elements, New York: Pergamon, 1984.
Ganjali, M.R., Mirnaghi, F., Norouzi, P., and Adib, M., Sens. Actuators B, 2006, vol. 115, p. 374.
Mittal, S.K. and Sharma, H.K., Res. J. Biotechnol., 2008, vol. 3, p. 470.
Zamani, H.A., Ganjali, M.R., Norouzi, P., and Meghdadi, S., Anal. Lett., 2008, vol. 41, p. 902.
Zamani, H.A., Masrournia, M., Sahebnasagh, S., and Ganjali, M.R., Anal. Lett., 2009, vol. 42, p. 555.
Chandra, S. and Singh, D.R., Chin. J. Chem., 2010, vol. 28, p. 833.
Harish, K.S., Neha, V., and Kapoor, J.K., E-J. Chem., 2011, vol. 8, p. S155.
Zamani, H.A., Arvinfar, A., Rahimi, F., Imani, A., Ganjali, M.R., and Meghdadi, S., Mater. Sci. Eng. C, 2011, vol. 31, p. 307.
Pourjavid, M.R., Rezaee, M., Hosseini, M.H., and Razavi, T., Quim. Nova, 2012, vol. 35, p. 1973.
Kamata, S., Bhale, A., Fukunaga, Y., and Murata, A., Anal. Chem., 1998, vol. 60, p. 2464.
Zamani, H.A., Naghavi-Reyabbi, F., Faridbod, F., Mohammadhosseini, M., Ganjali, M.R., Tadjarodi, A., and Rad, M., Mater. Sci. Eng. C, 2013, vol. 33, p. 870.
Zamani, H.A., Shoshtari, M.,, and Feizyzadeh, B., Int. J. Electrochem. Sci., 2015, vol. 10, p. 8644.
Zamani, H.A., Zanganeh-Asadabadi, A., Rohani, M., Zabihi, M.S., Fadaee, J., Ganjali, M.R., Faridbod, F., and Meghdadi, S., Mater. Sci. Eng. C, 2013, vol. 33, p. 984.
Zamani, H.A., Ganjali, M.R., Behmadi, H., and Behnajady, M.A., Mater. Sci. Eng. C, 2009, vol. 29, p. 1535.
Ganjali, M.R., Rouhollahi, A., Mardan, A.R., Hamzeloo, M., Mogimi, A., and Shamsipur, M., Microchem. J., 1998, vol. 60, p. 122.
Joz-Yarmohammadi, F., Zamani, H.A., and Mohammadabadi, F., Int. J. Electrochem. Sci., 2015, vol. 10, p. 8124.
Ganjali, M.R., Rasoolipour, S., Rezapour, M., Norouzi, P., Tajarodi, A., and Hanifehpour, Y., Electroanalysis, 2005, vol. 17, p. 1534.
Shirdel, A., Zamani, H.A., Joz-Yarmohammadi, F., Beyramabadi, S.A., and Abedi, M.R., J. Incl. Phenom. Macrocycl. Chem., 2016, vol. 86, p. 351.
Zamani, H.A., Ganjali, M.R., Faridbod, F., and Salavati-Niasari, M., Mater. Sci. Eng. C, 2012, vol. 32, p. 564.
Ganjali, M.R., Kiani-Anbouhi, R., Shamsipur, M., Poursaberi, T., Salavati-Niasari, M., and Talebpour, Z., Electroanalysis, 2004, vol. 16, p. 1002.
Ganjali, M.R., Ravanshad, J., Hosseini, M., Salavati-Niasari, M., Pourjavid, M.R., and Baezzat, M.R., Electroanalysis, 2004, vol. 16, p. 1771.
Zamani, H.A., Imani, A., Arvinfar, A., Rahimi, F., Ganjali, M.R., Faridbod, F., and Meghdadi, S., Mater. Sci. Eng. C, 2011, vol. 31, p. 588.
Mohammadabadi, F., Zamani, H.A., Joz-Yarmohammadi, F., and Abedi, M.R., Int. J. Electrochem. Sci., 2015, vol. 10, p. 2791.
Ganjali, M.R., Norouzi, P., Atrian, A., Faridbod, F., Meghdadi, S., and Giahi, M., Mater. Sci. Eng. C, 2009, vol. 29, p. 205.
Zamani, H.A., Ganjali, M.R., Norouzi, P., Tadjarodi, A., and Shahsavani, E., Mater. Sci. Eng. C, 2008, vol. 28, p. 1489.
Masrournia, M., Zamani, H.A., Mirrashid, H.A., Ganjali, M.R., and Faridbod, F., Mater. Sci. Eng. C, 2011, vol. 31, p. 574.
Zamani, H.A., Mohammadhossieni, M., Haji-Mohammadrezazadeh, S., Faridbod, F., Ganjali, M.R., Meghdadi, S., and Davoodnia, A., Mater. Sci. Eng. C, 2012, vol. 32, p. 712.
Zamani, H.A., Nekoei, M., Mohammadhosseini, M., and Ganjali, M.R., Mater. Sci. Eng. C, 2010, vol. 30, p. 480.
Zamani, H.A., Feizyzadeh, B., Faridbod, F., and Ganjali, M.R., Sensor Lett., 2011, vol. 9, p. 1767.
Zamani, H.A., Naghavi-Reyabbi, F., Mohammadhossieni, M., Feizyzadeh, B., Abedi, M.R., Faridbod, F., and Ganjali, M.R., Sensor Lett., 2012, vol. 10, p. 112.
Alizadeh, K., Parooi, R., Hashemi, P., Rezaei, B., and Ganjali, M.R., J. Hazard Mater., 2011, vol. 186, p. 1794.
Ebrahimi, M., Zamani, H.A., and Abedi, M.R., J. Indian Chem. Soc., 2014, vol. 91, p. 431.
Hosseini, M., Abkenar, S.D., Ganjali, M.R., and Faridbod, F., Mater. Sci. Eng. C: Mater., 2011, vol. 31, p. 428.
Zamani, H.A., Joz-Yarmohammadi, F., and Abedi, M.R., J. Indian Chem. Soc., 2016, vol. 93, p. 1035.
Moshirian Farahi, S., Zamani, H.A., Joz-Yarmohammadi, F., Abedi, M.R., and Behmadi, H., J. Indian Chem. Soc., 2016, vol. 93, p. 1139.
Ghasediana, F., Zamani, H.A., Joz-Yarmohammadi, F., Beyramabadi, S.A., and Abedi, M.R., Russ. J. Appl. Chem., 2016, vol. 89, p. 2001.
Umezawa, Y., Umezawa, K., and Sato, H., Pure Appl. Chem., 1995, vol. 67, p. 507.
Zamani, H.A., Zabihi, M.S., Rohani, M., Zangeneh-Asadabadi, A., Ganjali, M.R., Faridbod, F., and Meghdadi, S., Mater. Sci. Eng. C, 2011, vol. 31, p. 409.
Zamani, H.A., Rohani, M., Mohammadhosseini, M., Ganjali, M.R., Faridbod, F., and Meghdadi, S., Sensor Lett., 2011, vol. 9, p. 1745.
Zamani, H.A., Faridbod, F., and Ganjali, M.R., Mater. Sci. Eng. C, 2014, vol. 43, p. 488.
Dehnavi, A. and Zamani, H.A., Int. J. Electrochem. Sci., 2014, vol. 9, p. 8273.
Hatami, E., Zamani, H.A., and Sanavi-Khoshnod, R., Int. J. Electrochem. Sci., 2014, vol. 9, p. 8263.
Zamani, H.A., Ranjkesh, M., and Abedi, M.R., Int. J. Electrochem. Sci., 2014, vol. 9, p. 8435.
Zamani, H.A. and Faridbod, F., J. Anal. Chem., 2014, vol. 69, p. 1073.
Zamani, H.A., Faridbod, F., and Ganjali, M.R., Mater. Sci. Eng. C, 2013, vol. 33, p. 608.
Guilbault, G.G., Durst, R.A., Frant, M.S., Freiser, H., Hansen, E.H., Light, T.S., Pungor, E., Rechnitz, G., Rice, N.M., Rohm, T.J., Simon, W., and Thomas, J.D.R., Pure. Appl. Chem., 1976, vol. 46, p. 127.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Elektrokhimiya, 2017, Vol. 53, No. 5, pp. 497–504.
The article is published in the original.
Rights and permissions
About this article
Cite this article
Jahanian, L., Zamani, H.A., Joz-Yarmohammadi, F. et al. A new PVC matrix membrane sensor for determination of praseodymium(III) ion based on bis(salicylaldehyde)thiocarbohydrazone as an ion carrier. Russ J Electrochem 53, 435–442 (2017). https://doi.org/10.1134/S1023193517050068
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193517050068