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Ion conductivity of the plastic phase of the organic salt [(C4H9)4N]BF4

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Abstract

Based on the thermal and X-ray diffraction analysis, NMR spectroscopy, and ion conductivity data it was shown that the organic salt [n-Bu4N]BF4 has an orientationally disordered phase with a primitive cubic unit cell (space group \(P\bar 43n\); unit cell parameter a c = 1.4886(2) nm) in the temperature range 62–161°C. The mobility of molecular fragments and anions increased during the phase transition, and the ion conductivity was relatively high, reaching ∼10−6 S/cm at 150°C.

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References

  1. Kottas, G.S., Clarke, L.I., Horinek, D., and Michl, D., Chem. Rev., 2005, vol. 105, p. 1281.

    Article  CAS  Google Scholar 

  2. Parsonage, N.G. and Stavely, L.K., Disorder in Crystals, Oxford: Oxford Univ. Press, 1988.

    Google Scholar 

  3. Kvist, A. and Bengtzelius, A., in Fast Ion Transport in Solids, van Gool, W., Ed., Amsterdam: North-Holland, 1973, p. 141.

  4. Lunden, A., Solid State Commun., 1988, vol. 65, no. 10, p. 1237.

    Article  CAS  Google Scholar 

  5. Ulihin, A.S., Uvarov, N.F., and Mellander, B.E., Solid State Ionics, 2008, vol. 179, nos. 1–6, p. 228.

    Article  CAS  Google Scholar 

  6. Wilmer, D., Funke, K., Witschas, M., Banhatti, R.D., Jansen, M., Korus, G., Fitter, J., and Lecner, R.E., Physica B, 1999, vol. 266, p. 60.

    Article  CAS  Google Scholar 

  7. Uvarov, N.F., Ulikhin, A.S., Iskakova, A.A., Medvedev, N.N., and Anikeenko, A.N., Russ. J. Electrochem., 2011, vol. 47, p. 404.

    Article  CAS  Google Scholar 

  8. Uvarov, N.F., Iskakova, A.A., Ulihin, A.S., Medvedev, N.N., and Anikeenko, A.N., Solid State Ionics, 2011, vol. 188, no. 1, p. 78.

    Article  CAS  Google Scholar 

  9. Anikeenko, A.V., Medvedev, N.N., and Uvarov, N.F., Solid State Ionics, 2013, vol. 251, no. 15, p. 13.

    Article  CAS  Google Scholar 

  10. Shimizu, T., Tanaka, S., Onoda-Yamamuro, N., Ishimaru, S., and Ikeda, R., J. Chem. Soc., Faraday Trans., 1997, vol. 93, no. 2, p. 321.

    Article  CAS  Google Scholar 

  11. Zdanovska-Fraczek, M., Holderna-Natkaniec, K., Fraczek, Z.J., and Jakubas, R., Solid State Ionics, 2009, vol. 180, no. 1, p. 9.

    Article  Google Scholar 

  12. Sun, J., MacFarlane, D.R., and Forsyth, M., Solid State Ionics, 2002, vol. 148, nos. 1–2, p. 145.

    Article  CAS  Google Scholar 

  13. Pringle, J.M., Howlett, P.C., MacFarlane, D.R., and Forsyth, M., J. Mater. Chem., 2010, vol. 20, p. 2056.

    Article  CAS  Google Scholar 

  14. Seeber, A.J., Forsyth, M., Forsyth, C.M., Forsyth, S.A., Annat, G., and MacFarlane, D.R., Phys. Chem. Chem. Phys., 2003, vol. 5, p. 2692.

    Article  CAS  Google Scholar 

  15. Hill, A.J., Huang, J., Efthimiadis, J., Meakin, P., Forsyth, M., and MacFarlane, D.R., Solid State Ionics, 2002, vol. 154, p. 119.

    Article  Google Scholar 

  16. Pas, S.J., Huang, J., Forsyth, M., MacFarlane, D.R., and Hull, A.J, J. Chem. Phys., 2005, vol. 122, p. 064704.

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630128, Russia

    N. F. Uvarov, A. A. Iskakova, N. V. Bulina & K. B. Gerasimov

  2. Novosibirsk State University, Novosibirsk, 630090, Russia

    N. F. Uvarov

  3. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, 690022, Russia

    A. B. Slobodyuk & V. Ya. Kavun

Authors
  1. N. F. Uvarov
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  2. A. A. Iskakova
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  3. N. V. Bulina
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  4. K. B. Gerasimov
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  5. A. B. Slobodyuk
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  6. V. Ya. Kavun
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Correspondence to N. F. Uvarov.

Additional information

Original Russian Text © N.F. Uvarov, A.A. Iskakova, N.V. Bulina, K.B. Gerasimov, A.B. Slobodyuk, V.Ya. Kavun, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 5, pp. 564–568.

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Uvarov, N.F., Iskakova, A.A., Bulina, N.V. et al. Ion conductivity of the plastic phase of the organic salt [(C4H9)4N]BF4 . Russ J Electrochem 51, 491–494 (2015). https://doi.org/10.1134/S102319351505016X

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  • DOI: https://doi.org/10.1134/S102319351505016X

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