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Comparative study of the ion conductivities of substituted tetrabutylammonium salts (C4H9)4N]BF4 and [(C4H9)4N]Br

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Abstract

The ion conductivity of the salts [(C4H9)4N]BF4 and [(C4H9)4N]Br was studied in vacuum at temperatures from room temperature to 190 and 135°C, respectively. The salts have phase transitions to disordered high-temperature phases accompanied by an increase in conductivity. [(C4H9)4N]Br has higher conductivity than [(C4H9)4N]BF4. As the conductivity decreases with the increasing size of the anion, the BF4 – and Br– anions are the most probable current carriers in the salts.

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Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630128, Russia

    A. A. Iskakova, A. S. Ulikhin, N. F. Uvarov, K. B. Gerasimov & Yu. G. Mateishina

  2. Novosibirsk State Technical University, Novosibirsk, 630073, Russia

    N. F. Uvarov

  3. Novosibirsk State University, Novosibirsk, 630090, Russia

    N. F. Uvarov

Authors
  1. A. A. Iskakova
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  2. A. S. Ulikhin
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  3. N. F. Uvarov
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  4. K. B. Gerasimov
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  5. Yu. G. Mateishina
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Correspondence to A. A. Iskakova.

Additional information

Published on the basis of a report delivered at the 13th International Meeting “Fundamental Problems of Solid State Ionics,” Chernogolovka, 2016.

Original Russian Text © A.A. Iskakova, A.S. Ulikhin, N.F. Uvarov, K.B. Gerasimov, Yu.G. Mateishina, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 8, pp. 987–990.

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Iskakova, A.A., Ulikhin, A.S., Uvarov, N.F. et al. Comparative study of the ion conductivities of substituted tetrabutylammonium salts (C4H9)4N]BF4 and [(C4H9)4N]Br. Russ J Electrochem 53, 880–883 (2017). https://doi.org/10.1134/S1023193517080079

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  • DOI: https://doi.org/10.1134/S1023193517080079

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