Abstract
In recent years, nanocomposites based on biodegradable polymer and clay have received increasing interest and their development has become a very hot topic. Herein, it is reported a sustainable route across simple, lucrative ways and at low cost for synthesizing zeolite (sodalite), polycaprolactone and based polycaprolactone/sodalite nanocomposite. Sodalite was prepared from a broadly available kaolin depot from the west Algeria. Physical and chemical characteristics of the synthesized nanocomposite and its components are qualified using XRF, BET, TGA, XRD, SEM, AFM, and FTIR. Moreover, this article also includes a simple method for preparing dry powder specimens to AFM analysis, which showed a decrease in the surface roughness from kaolin to nanocomposite through zeolite. This research suggests the use of synthesized materials sodalite and nanocomposite as adsorbents for environmental remediation to eliminate pollutants due to their important measured characteristics for synthesized materials such as BET surface.
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REFERENCES
D. Rickerby and M. Morrison, Sci. Technol. Adv. Mater. 8, 19 (2007). https://doi.org/10.1016/j.stam.2006.10.002
G. Brumfiel, Nature (London, U.K.) 424, 246 (2003). https://doi.org/10.1038/424246a
S. Ramakrishna, K. Fujihara, W. E. Teo, T. C. Lim, and Z. Ma, An Introduction to Electrospinning and Nanofibers (World Scientific, Singapore, 2005). https://doi.org/10.1142/5894
H. Saleem, S. J. Zaidi, A. F. Ismail, and P. S. Goh, Chemosphere 287, 132083 (2022). https://doi.org/10.1016/j.chemosphere.2021.132083
N. Yadav, V. K. Garg, A. K. Chhillar, and J. S. Rana, Chemosphere 280, 130792 (2021). https://doi.org/10.1016/j.chemosphere.2021.130792
S. Z. Mohammadi, Z. Darijani, and M. A. Karimi, Russ. J. Phys. Chem. A 95, S33 (2021). https://doi.org/10.1134/S0036024421140144
I. Ali, Chem. Rev. 112, 5073 (2012). https://doi.org/10.1021/cr300133d
H. Sadegh, G. A. M. Ali, V. K. Gupta, A. S. H. Makhlouf, R. S. Ghoshekandi, M. N. Nadagouda, M. Sillanpa, and E. Z. Megiel, J. Nanostruct. Chem. 7, 1 (2017). https://doi.org/10.1007/s40097-017-0219-4
A. Kumari, S. K. Yadav, and S. C. Yadav, Colloids Surf., B 75, 1 (2010). https://doi.org/10.1016/j.colsurfb.2009.09.001
M. R. Tavares, L. R. de Menezes, D. F. do Nascimento, D. H. S. Souza, F. Reynaud, M. F. V. Marques, and M. I. B. Tavares, Eur. Phys. J. Spec. Top. 225, 779 (2016). https://doi.org/10.1140/epjst/e2015-50266-2
D. Mondal, M. Griffith, and S. S. Venkatraman, Int. J. Polym. Mat. Polym. Biomater. 65, 255 (2016). https://doi.org/10.1080/00914037.2015.1103241
C. Parisi, G. Longobardi, A. C. E. Graziano, A. Fraix, C. Conte, F. Quaglia, and S. Sortino, Bioorg. Chem. 128, 106 (2022). https://doi.org/10.1016/j.bioorg.2022.106050
N. H. Mthombeni, S. Mbakop, and M. S. Onyango, Int. J. Environ. Sci. Dev. 6, 602 (2015). https://doi.org/10.7763/IJESD.2015.V6.665
D. Zadaka-Amir, A. Nasser, S. Nir, and Y. G. Mishael, Microporous Mesoporous Mater. 151, 216 (2012). https://doi.org/10.1016/j.micromeso.2011.10.033
K.-H. Chung, D. R. Chang, and B. G. Park, Bioresour. Technol. 99, 7438 (2008). https://doi.org/10.1016/j.biortech.2008.02.031
M. Pansini, Miner. Depos. 31, 563 (1996). https://doi.org/10.1007/BF00196137
K. M. Roghayeh and S. A. Fakhry, Microporous Mesoporous Mater. 120, 285 (2009). https://doi.org/10.1016/j.micromeso.2008.11.027
C. Colella, Miner. Depos. 31, 554 (1996). https://doi.org/10.1007/BF00196136
S. A. Nabi, M. Shahadat, R. Bushra, A. H. Shalla, and A. Azam, Colloids Surf., B 87, 122 (2011). https://doi.org/10.1016/j.colsurfb.2011.05.011
J. Gascon, F. Kapteijn, B. Zornoza, V. Sebastien, C. Casado, and J. Coronas, Chem. Mater. 24, 2829 (2012). https://doi.org/10.1021/cm301435j
H. Peng, T. Qi, J. Vogrin, Q. Huang, W. Wu, and J. Vaughan, Miner. Eng. 170, 107071 (2021). https://doi.org/10.1016/j.mineng.2021.107071
Q. Song, J. Shen, Y. Yang, J. Wang, Y. Yang, J. Sun, B. Jiang, and Z. Liao, Microporous Mesoporous Mater. 292, 109755 (2020). https://doi.org/10.1016/j.micromeso.2019.109755
C. Belviso, F. Cavalcante, A. Lettino, and S. Fiore, Appl. Clay Sci. 80, 162 (2013). https://doi.org/10.1016/j.clay.2013.02.003
A. A. B. Maia, R. F. Neves, R. S. Angelica, and H. Pollmann, Clay Miner. 50, 663 (2015). https://doi.org/10.1180/claymin.2015.050.5.09
F. A. C. M. Passos, D. C. Castro, K. K. Ferreira, K. M. A. Simoes, L. C. Bertolino, C. N. Barbato, F. M. S. Garrido, A. A. S. Felix, and F. A. N. G. Silva, in Characterization of Minerals, Metals, and Materials, Conference Paper, Part of: The Minerals, Metals, and Materials Series (Springer, Cham, 2017), p. 279. https://doi.org/10.1007/978-3-319-51382-9_31
A. V. Borhade, S. G. Wakchaure, A. G. Dholi, and T. A. Kshirsagar, Russ. J. Phys. Chem. A 91, 1183 (2017). https://doi.org/10.1134/S0036024417070081
W. Franus, M. Wdowin, and M. Franus, Environ. Monit. Assess. 186, 5721 (2014). https://doi.org/10.1007/s10661-014-3815-5
A. V. Borhade, T. A. Kshirsagar, and A. G. Dholi, Arab. J. Sci. Eng. 42, 4479 (2017). https://doi.org/10.1007/s13369-017-2759-9
S. Zuo, W. Liu, C. Yao, X. Li, S. Luo, F. Wu, Y. Kong, and X. Liu, Appl. Clay Sci. 119, 170 (2016). https://doi.org/10.1016/j.clay.2015.08.029
M. Kaiheriman, A. Sidike, A. Maimaitinasier, A. Reheman, and B. Rouzi, J. Lumin. 157, 411 (2015). https://doi.org/10.1016/j.jlumin.2014.08.028
F. Liu, L. L. Liu, D. Xue, and F.-X. Li, J. Fuel Chem. Technol. 44, 477 (2016). https://doi.org/10.1016/S1872-5813(16)30023-8
A. V. Borhade, A. G. Dholi, and T. A. Kshirsagar, Russ. J. Phys. Chem. A 94, 370 (2020). https://doi.org/10.1134/S0036024420020065
A. Finch, Mineral. Mag. 55, 459 (1991). https://doi.org/10.1180/minmag.1991.055.380.15
Database of Raman Spectroscopy, X-ray Diffraction and Chemistry of Minerals. http://rruff.geo.arizona.edu/AMS/viewJmol.php?amcsd=0018028. Accessed June 30, 2022.
C. Belviso, F. Cavalcante, A. Lettino, and S. Fiore, Appl. Clay Sci. 80, 162 (2013). https://doi.org/10.1016/j.clay.2013.02.003
M. Irandoost, M. P. Modaress, and V. Javanbakht, J. Water Process. Eng. 32, 100981 (2019). https://doi.org/10.1016/j.jwpe.2019.100981
S. P. Bao, S. C. Tjong, and C. Y. Tang, in Physical Properties and Applications of Polymer Nanocomposites, Woodhead Publishing Series in Composites Science and Engineering, Ed. by Tjong and Y. W. Mai (Woodhead, Cambridge, 2010), p. 280. https://doi.org/10.1533/9780857090249.2.280
A. Hejna, Ł. Zedler, M. P. Romatowska, J. Cañavate, X. Colom, and K Formela, Polymers 12, 1204 (2020). https://doi.org/10.3390/polym12051204
G. Anbalagan, A. R. Prabakaran, and S. Gunasekaran, J. Appl. Spectrosc. 77, 86 (2010). https://doi.org/10.1007/s10812-010-9297-5
B. Jaleh and P. Fakhri, in Spectroscopy of Polymer Nanocomposites, Ed. by S. Thomas, D. Rouxel, and D. Ponnamma (William Andrew, 2016), Chap. 5, p. 112. https://doi.org/10.1016/B978-0-323-40183-8.00005-7
R. Augustine, H. N. Malik, D. K. Singhal, D. K. A. Mukherjee, D. Malakar, N. Kalarikkal, and S. Thomas, J. Polym. Res. 21, 347 (2014). https://doi.org/10.1007/s10965-013-0347-6
N. Doebelin and R. Kleeberg, J. Appl. Crystallogr. 48, 1573 (2015). https://doi.org/10.1107/S1600576715014685
N. A. Sholeha, L. Jannah, N. H. Rohma, N. Widiastuti, D. Prasetyoko, A. A. Jalil, and H. Bahruji, Clays Clay Miner. 68, 513 (2020). https://doi.org/10.1007/s42860-020-00089-3
S. Otieno, C. Kowenje, F. Kengara, and R. Mokaya, Mater. Adv. 2, 5997 (2021). https://doi.org/10.1039/D1MA00449B
I. Hassan, S. M. Antao, and J. B. Parise, Am. Mineral. 89, 359 (2004). https://doi.org/10.2138/am-2004-2-315
N. M. Musyoka, Ph. D. Thesis (Univ. Western Cape, Cape Town, South Africa, 2009).
L. Cui, R. Han, L. Yang, Y. Wu, R. Pei, and F. Li, Microporous Mesoporous Mater. 306, 110385 (2020). https://doi.org/10.1016/j.micromeso.2020.110385
H. Y. Kim, B. H. Kim, and M. S. Kim, Materials 15, 366 (2022). https://doi.org/10.3390/ma15010366
A. Baji, S. C. Wong, T. Liu, T. Li, and T. S. Srivatsan, J. Biomed. Mater. Res. B 81, 343 (2007). https://doi.org/10.1002/jbm.b.30671
M. S. de S. de B. Monteiro, C. L. Rodrigues, Mater. Sci. Appl. 7, 575 (2016). https://doi.org/10.4236/msa.2016.710048
Y. Huang, N. Dan, W. Dan, and W. Zhao, ACS Omega 4, 22292 (2019). https://doi.org/10.1021/acsomega.9b02217
R. Balan and V. Gayathri, Polym. Bull. 79, 4269 (2022). https://doi.org/10.1007/s00289-021-03707-9
W. Sas, M. J. Delaporte, P. Czaja, P. M. Z. Nski, and M. Fitta, Magnetochemistry 7, 61 (2021). https://doi.org/10.3390/magnetochemistry7050061
A. S. Hadj-Hamou, F. Metref, and F. Yahiaoui, Polym. Bull. 74, 3833 (2017). https://doi.org/10.1007/s00289-017-1929-y
T. Elzein, M. Nasser-Eddine, C. Delaite, S. Bistac, and P. Dumas, J. Colloid Interface Sci. 273, 381 (2004). https://doi.org/10.1016/j.jcis.2004.02.001
S. Brunauer, P. H. Emmet, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938). https://doi.org/10.1021/ja01269a023
Z. Tauanov, P. E. Tsakiridis, D. Shah, and V. J. Inglezakis, J. Environ. Sci. Health A 54, 95 (2019). https://doi.org/10.1080/10934529.2019.1611129
M. C. Manique, L. V. Lacerda, A. K. Alves, and C. P. Bergmann, Fuel 190, 268 (2017). https://doi.org/10.1016/j.fuel.2016.11.016
S. Zeng, R. Wang, Z. Zhang, and S. Qiu, Inorg. Chem. Commun. 70, 168 (2016). https://doi.org/10.1016/j.inoche.2016.06.013
J. Li, X. Zeng, X. Yang, C. Wang, and X. Luo, Mater. Lett. 161, 157 (2015). https://doi.org/10.1016/j.matlet.2015.08.058
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Kenza, E., Wafa, A., Abdelhafid, Z. et al. Synthesis and Characterization of Nanocomposite Based on Sodalite and Polycaprolactone. Russ. J. Phys. Chem. 97, 1532–1541 (2023). https://doi.org/10.1134/S0036024423070075
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DOI: https://doi.org/10.1134/S0036024423070075