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Physiсo-Chemical Investigations on the Catalytic Production of Biofuel from Algal Biomass

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Abstract

Energy crises and growing demand for energy has increased the importance of biodiesel from algae, because renewable, carbon neutral, transport fuels are necessary for environmental and economic sustainability. This study was undertaken to know the proper production of biodiesel from algae. The Spirogyra species of algae was used in the gasification process in the presence of catalyst. For this purpose cobalt/calcium oxide nanoparticles were prepared by co-precipitation, characterized and were then used for catalytic gasification of algae at temperature of 300°C. The catalyst increased the oil content at low temperature and the products obtained were bio-oil and biochar to be used as bio-fertilizer. Cobalt oxide and calcium oxide nanoparticles were used due to their reactivity with high surface area which decrease the activation energy and reaction temperature. Bio-oil was transesterified to convert it into biodiesel by using sodium hydroxide catalyst and methanol. These results were confirmed through using various techniques like Fourier infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), gas chromatography–mass spectrometry (GCMS), and particle-induced X-ray emission (PIXE). Results not only confirmed the successful production of oil but also indicated that the nano-catalyst showed good efficiency and increased the oil content at a relatively lower temperature.

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REFERENCES

  1. R. Bhateriaa and R. Dhakaa, Biofuels 5, 607 (2014).

    Article  Google Scholar 

  2. A. V. Grigorenko, Yu. I. Kostyukevich, N. I. Chernova, et al., Russ. J. Appl. Chem. 92, 1480 (2019).

    Article  CAS  Google Scholar 

  3. B. Wang, Y. Li, N. Wu, and C. Q. Lan, Appl. Microbiol. Biotechnol. 79, 707 (2008).

    Article  CAS  Google Scholar 

  4. J. de Vrieze, K. Verbeeck, I. Pikaar, J. Boere, et al., New Biotechnol. 55, 12 (2020).

    Article  CAS  Google Scholar 

  5. K. Lee, Y. Hwang, S. Cheong, Y. Choi, L. Kwon, J. Lee, et al., Tribol. Lett. 35, 127 (2009).

    Article  CAS  Google Scholar 

  6. B. J. Gallagher, Renew. Energy 36, 158 (2011).

    Article  CAS  Google Scholar 

  7. A. Kleinová, Z. Cvengrošová, J. Rimarčík, et al., Proc. Eng. 42, 231 (2012).

    Article  Google Scholar 

  8. E. E. Kwon, Y. J. Jeon, and H. Yi, Bioresour. Technol. 123, 673 (2012).

    Article  CAS  Google Scholar 

  9. K. Chaiwong, T. Kiatsiriroat, N. Vorayos, and C. Thararax, Maejo Int. J. Sci. Technol. 6, 186 (2012).

    CAS  Google Scholar 

  10. S. Grierson, V. Strezov, and P. Shah, Bioresour. Technol. 102, 8232 (2011).

    Article  CAS  Google Scholar 

  11. E. S. Umdu, M. Tuncer, and E. Seker, Bioresour. Technol. 100, 2828 (2009).

    Article  CAS  Google Scholar 

  12. R. Maceiras, M. Rodríguez, A. Cancela, et al., Appl. Energy 88, 3318 (2011).

    Article  CAS  Google Scholar 

  13. D. Velentina, M. T. Abhishek, J. B. Manash, et al., Renew. Energy 161, 1110 (2020).

    Article  Google Scholar 

  14. M. Fatimatul, K. M. Laila, T. Triwikantoro, and A. Zaenal, J. Pena Sains. 5, 65 (2018).

  15. V. I. Anikeev and E. Y. Yakovleva, Russ. J. Phys. Chem. 86, 1646 (2012).

    Article  CAS  Google Scholar 

  16. S. H. Kong, S. K. Loh, R. T. Bachmann, et al., Renewable Sustainable Energy Rev. 39, 729 (2014).

    Article  CAS  Google Scholar 

  17. A. Sharma, V. Pareek, and D. Zhang, Renew. Sustain. Energy Rev. 50, 1081 (2015).

    Article  CAS  Google Scholar 

  18. C. A. Masiello, Mar. Chem. 92, 201 (2004).

    Article  CAS  Google Scholar 

  19. M. Inyang and E. Dickenson, Chemosphere 134, 232 (2015).

    Article  CAS  Google Scholar 

  20. M. Uchimiya, S. Hiradate, and J. M. J. Antal, ACS Sustain. Chem. Eng. 3, 1642 (2015).

    Article  CAS  Google Scholar 

  21. S. Jeffery, F. G. Verheijen, V. M. van der Velde, and A. C. Bastos, Agric. Ecosyst. Environ. 144, 175 (2011).

    Article  Google Scholar 

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Correspondence to Abbas Khan.

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Yaseen, M., Khattak, M.A., Khan, A. et al. Physiсo-Chemical Investigations on the Catalytic Production of Biofuel from Algal Biomass. Russ. J. Phys. Chem. 96 (Suppl 1), S31–S37 (2022). https://doi.org/10.1134/S0036024422140308

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  • DOI: https://doi.org/10.1134/S0036024422140308

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