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Transformations of the Lignin–Carbohydrate Complex of Triticum L . during Delignification with Ozone

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

The transformations of wheat straw (Triticum L.) treated with ozone were studied by Raman spectroscopy and synchronous thermogravimetric analysis combined with mass spectrometric analysis of products. For lignocellulose material (LCM) samples characterized by different specific ozone consumptions, Raman spectra were obtained. The DSC, TG, and DTG curves, as well as the profiles of the uncondensed products of thermal degradation released in an inert atmosphere, were analyzed. It was shown that ozonation results not only in the ozonolytic destruction of lignin, but also in the destruction of the entire lignin–carbohydrate matrix with release of some part of lignin-bound hemicelluloses; the proportion of cellulose in the ozonized LCMs increased, and there were no changes in the supramolecular structure of cellulose.

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ACKNOWLEDGMENTS

We are grateful to Prof. N.G. Bazarnova, Altai State University, for providing us with wheat straw samples.

Funding

This study was performed using the equipment of the Nanochemistry and Nanomaterials Multiaccess Center of the Faculty of Chemistry, Moscow State University. It was financially supported by the Ministry of Education and Science of the Russian Federation (state budget topic “Physical chemistry of surface, adsorption, and catalysis” АААА-А21-121011990019-4).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119992, Moscow, Russia

    N. A. Mamleeva, E. M. Ben’ko, A. N. Kharlanov & A. V. Shumyantsev

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  1. N. A. Mamleeva
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  2. E. M. Ben’ko
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  3. A. N. Kharlanov
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  4. A. V. Shumyantsev
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Corresponding author

Correspondence to N. A. Mamleeva.

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The authors declare that they have no conflicts of interest.

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Translated by L. Smolina

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Mamleeva, N.A., Ben’ko, E.M., Kharlanov, A.N. et al. Transformations of the Lignin–Carbohydrate Complex of Triticum L . during Delignification with Ozone . Russ. J. Phys. Chem. 96, 2358–2366 (2022). https://doi.org/10.1134/S003602442211019X

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