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Facile Synthesis of Microporous Bi2O3 Crystals for Li Ion Full Battery

  • COLLOID CHEMISTRY AND ELECTROCHEMISTRY
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Abstract

One-step facile synthesis of microporous mix-crystals of α−, β-, and γ-Bi2O3 is proposed by the thermal decomposition of bismuth nitrate, and the microporous Bi2O3 mix-crystals are characterized by scanning electron microscope, X-ray powder diffractometer, Fourier transform infrared spectrometer, thermogravimeter and differential scanning calorimeter, and Brunauer–Emmett–Teller surface area measurements. A long life Li ion full battery is constructed with the microporous Bi2O3 mix-crystals as cathode and the porous lithium foil/Li-graphite as anode. The full battery is tested by the galvanostatic current charge-discharge technology at higher current densities of 0.5 mA cm–2. The microporous Bi2O3 mix-crystals and lithium foil-graphite can effectively improve the discharge capacity and cycle life of full battery.

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ACKNOWLEDGMENTS

The authors gratefully acknowledge the financial support of the Open Science Foundation for Jiangsu Province Key Laboratory for Chemistry of Low-Dimentional Materials (grant no. JSKC17009), the Open Science Foundation for Jiangsu Key Laboratory for Biomass–based Energy and Enzyme Technology (grant no. JSBEET1207), and the Science foundation for Huaiyin Normal University (grant no. 11HSGJBZ13).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Huaiyin Normal University, Jiangsu Province Key Laboratory for Chemistry of Low-Dimentional Materials, 223300, Huai An, China

    Y. Z. Song, B. X. Qi & Mengting Li

  2. School of Chemistry and Chemical Engineering, Jiangsu University, 212013, Zhenjiang, China

    Jimin Xie

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  1. Y. Z. Song
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  2. B. X. Qi
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  3. Mengting Li
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Correspondence to Y. Z. Song or Jimin Xie.

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Song, Y.Z., Qi, B.X., Li, M. et al. Facile Synthesis of Microporous Bi2O3 Crystals for Li Ion Full Battery. Russ. J. Phys. Chem. 96, 1582–1588 (2022). https://doi.org/10.1134/S0036024422070287

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  • DOI: https://doi.org/10.1134/S0036024422070287

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