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Driving Forces of the Self-Assembly of Supramolecular Systems: Partially Ordered Mesophases

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Abstract

The main aspects are considered of the self-organization of a new class of liquid crystalline compounds, rigid sector-shaped and cone-shaped dendrons. Theoretical approaches to the self-assembly of different amphiphilic compounds (lipids, bolaamphiphiles, block copolymers, and polyelectrolytes) are described. Particular attention is given to the mesophase structures that emerge during the self-organization of mesophases characterized by intermediate degrees of ordering, e.g., plastic crystals, the rotation-crystalline phase in polymers, ordered and disordered two-dimensional columnar phases, and bicontinuous cubic phases of different symmetry.

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Correspondence to M. A. Shcherbina.

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Original Russian Text © M.A. Shcherbina, S.N. Chvalun, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 6, pp. 976–986.

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Shcherbina, M.A., Chvalun, S.N. Driving Forces of the Self-Assembly of Supramolecular Systems: Partially Ordered Mesophases. Russ. J. Phys. Chem. 92, 1161–1170 (2018). https://doi.org/10.1134/S003602441806016X

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  • DOI: https://doi.org/10.1134/S003602441806016X

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