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Glass Formation in the MgC6H6O7–H2O System: Synthesis of Amorphous Magnesium Citrate

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

In the MgC6H6O7–H2O system, glass formation was detected for the first time, and the boundaries of the glass formation region were found to be in the range from 50 to 77 wt % MgC6H6O7. Glass-forming samples and the amorphous water-soluble compound MgC6H6O7 obtained by dehydration of the glass of the composition MgC6H6O7⋅3.5H2O at 40°C were studied by X-ray powder diffraction analysis, IR spectroscopy, and differential scanning calorimetry. The compositions of glass-forming samples resistant to crystallization were determined. The criterion for the crystallization resistance of glasses is the absence of crystallization during heating. The thermal curves of such glasses show only the event of Tg.

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ACKNOWLEDGMENTS

We thank Dr. Sci. (Chem.) I. A. Efimenko and Cand. Sci. (Chem.) I. S. Ivanova for valuable remarks made during the preparation of the article for publication.

Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation under a state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow Russia.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. A. Kirilenko & V. P. Danilov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    L. I. Demina

Authors
  1. I. A. Kirilenko
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  2. L. I. Demina
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  3. V. P. Danilov
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Correspondence to I. A. Kirilenko.

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Translated by V. Glyanchenko

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Kirilenko, I.A., Demina, L.I. & Danilov, V.P. Glass Formation in the MgC6H6O7–H2O System: Synthesis of Amorphous Magnesium Citrate. Russ. J. Inorg. Chem. 67, 1731–1738 (2022). https://doi.org/10.1134/S0036023622700073

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