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Low-Frequency Raman Lines as an Indicator of the Presence of Lead in Oxide Materials

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Abstract

Raman spectra were obtained for single- and polycrystalline specimens of some oxide compounds used as quantum electronic materials and for native minerals containing complex anions, where the cations are alkaline-earth metals and lead. An analysis of the low-frequency regions of the Raman spectra showed that, in some cases, the pair of high-intensity lines appearing in the range below 100 cm–1 serves as an indicator of the presence of Pb2+ ions.

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REFERENCES

  1. D. Bersani and J. M. Madariaga, J. Raman Spectrosc. 43, 1523 (2012). https://doi.org/10.1002/jrs.4219

    Article  CAS  Google Scholar 

  2. D. Yang and Y. Ying, Appl. Spectrosc. Rev. 46, 539 (2011). https://doi.org/10.1080/05704928.2011.593216

    Article  Google Scholar 

  3. T. T. Basiev, Phys.-Usp. 42, 1051 (1999). https://doi.org/10.1070/PU1999v042n10ABEH000663

    Article  CAS  Google Scholar 

  4. L. I. Ivleva, I. S. Voronina, P. A. Lykov, et al., J. Cryst. Growth 304, 108 (2007). https://doi.org/10.1016/j.jcrysgro.2007.02.020

    Article  CAS  Google Scholar 

  5. H. Poulet and J. P. Mathieu, Spectres de Vibration et Symetrie des Cristaux (Gordon & Breach, 1970; Mir, Moscow, 1973).

  6. G. E. Kugel, F. Brehat, B. Wyncke, et al., J. Phys. C: Solid State Phys. 21, 5565 (1988). https://doi.org/10.1088/0022-3719/21/32/011

    Article  CAS  Google Scholar 

  7. Yu. K. Voron’ko and A. A. Sobol’, Inorg. Mater. 41, 420 (2005).

    Article  Google Scholar 

  8. A. H. Pandey, V. Sathe, and S. M. Gupta, Proceedings of the National Laser Symposium (NLS-2015).

  9. N. Waeselmann, B. Mihailova, M. Gospodinov, and U. Bismayer, J. Phys.: Condens. Matter 25, 155 902 (2013). https://doi.org/10.1088/0953-8984/25/15/155902

    Article  CAS  Google Scholar 

  10. A. G. Souza Filho et al., J. Phys.: Condens. Matter 13, 7305 (2001).

    CAS  Google Scholar 

  11. Yu. K. Voron’ko, B. F. Dzhurinskii, A. E. Kokh, et al., Inorg. Mater. 41, 984 (2005).

    Article  Google Scholar 

  12. R. Frost and P. Williams, Spectrochim. Acta A 60 (8–9), 207 (2004). https://doi.org/10.1016/j.saa.2003.11.007

    Article  CAS  Google Scholar 

  13. A. Rulmont, Spectrochim. Acta A 34, 1117 (1978).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors are greatly thankful to L.I. Ivleva for providing barium tungstate single-crystal specimens.

Funding

This study was supported by the Russian Foundation for Basic Research (project No. 17-02-00518).

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Correspondence to P. P. Fedorov.

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Translated by O. Fedorova

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Shukshin, V.E., Fedorov, P.P. & Generalov, M.E. Low-Frequency Raman Lines as an Indicator of the Presence of Lead in Oxide Materials. Russ. J. Inorg. Chem. 64, 1442–1445 (2019). https://doi.org/10.1134/S0036023619100140

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  • DOI: https://doi.org/10.1134/S0036023619100140

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