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Gel formation during sol–gel synthesis of silicon dioxide

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The effects of water and catalyst (formic acid) concentrations and temperature on tetraethoxysilane hydrolysis, followed by gel formation, have been studied. The catalyst concentration is found to have a stronger effect on the variation rate of dynamic viscosity of the system compared to the effect of water concentration. The thermal behavior of the thus-prepared xerogels has been studied in an air flow; distinctions have been noticed for samples whose initial dispersion-bound systems were formed at room temperature.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. P. Simonenko, A. V. Derbenev, N. P. Simonenko, V. G. Sevastyanov & N. T. Kuznetsov

  2. Samara State Aerospace University (National Research University), Samara, Russia

    E. P. Simonenko, V. G. Sevastyanov & N. T. Kuznetsov

Authors
  1. E. P. Simonenko
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  2. A. V. Derbenev
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  3. N. P. Simonenko
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  4. V. G. Sevastyanov
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  5. N. T. Kuznetsov
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Corresponding author

Correspondence to V. G. Sevastyanov.

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Original Russian Text © E.P. Simonenko, A.V. Derbenev, N.P. Simonenko, V.G. Sevastyanov, N.T. Kuznetsov, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 12, pp. 1579–1587.

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Simonenko, E.P., Derbenev, A.V., Simonenko, N.P. et al. Gel formation during sol–gel synthesis of silicon dioxide. Russ. J. Inorg. Chem. 60, 1444–1451 (2015). https://doi.org/10.1134/S0036023615120220

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  • DOI: https://doi.org/10.1134/S0036023615120220

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