Abstract
The structure and optical properties of the Mn2FeAl Heusler alloy have been investigated. It is shown that the alloy crystallizes into a structure of the β-Mn type. The behavior of the optical conductivity of the alloy, which is anomalous for metallic systems (namely, the absence of a contribution from the intraband absorption and the presence of the intensive interband absorption), is observed in the IR spectral range. It is shown that this behavior is due to the following peculiarities of the electronic structure: the Fermi level is located in the region of a high density of states formed by the d states of Mn and Fe atoms.
Similar content being viewed by others
REFERENCES
S. Dash, A. V. Lukoyanov, N. D. Mishra, U. P. Mohammed Rasi, R. B. Gangineni, M. Vasundhara, and A. K. Patra, “Structural stability and magnetic properties of Mn2FeAl alloy with a β-Mn structure,” J. Magn. Magn. Mater. 513, 167205 (2020).
V. V. Marchenkov, V. Yu. Irkhin, Yu. A. Perevozchikova, P. B. Terent’ev, A. A. Semyannikova, E. B. Marchenkova, and M. Eisterer, “Kinetic properties and half-metallic magnetism in Mn2 YAl Heusler alloys,” J. Exp. Theor. Phys. 128, 919–925 (2019).
L. Wollmann, S. Chadov, J. Kübler, and C. Felser, “Magnetism in cubic manganese-rich Heusler compounds,” Phys. Rev. B. 90, 214420 (2014).
Z.-J. Yang, Q.-H. Gao, H.-N. Xiong, J.-X. Shao, X.‑W. Wang, and Z.-J. Xu, “Pressure-induced magnetic moment abnormal increase in Mn2FeAl and non-continuing decrease in Fe2MnAl via first principles,” Sci. Rep. 7, 16522 (2017).
H. Z. Luo, H. W. Zhang, Z. Y. Zhu, L. Ma, S. F. Xu, G. H. Wu, X. X. Zhu, C. B. Jiang, and H. B. Xu, “Half-metallic properties for the Mn2FeZ (Z = Al, Ga, Si, Ge, Sb) Heusler alloys: a first-principles study,” J. Appl. Phys. 103, 083908 (2008).
I. Jum’h, S. Sâadessaoud, H. Baaziz, Z. Charifi, and A. Telfah, “Electronic and magnetic structure and elastic and thermal properties of Mn2-based full Heusler alloys,” J. Supercond. Novel Magn. 32, 3915–3926 (2019). https://doi.org/10.1007/s10948-019-5095-3
C. Felser, L. Wollmann, S. Chadov, G. H. Fecher, and S. S. P. Parkin, “Basics and prospective of magnetic Heusler compounds,” APL Mater. 3, 041518 (2015).
I. Gavrikov, M. Seredina, M. Zheleznyy, I. Shchetinin, D. Karpenkov, A. Bogach, R. Chatterjee, and V. Khovaylo, “Magnetic and transport properties of Mn2FeAl,” J. Magn. Magn. Mater. 478, 55–58 (2019).
V. Yu. Irkhin and M. I. Katsnelson, “Temperature dependences of resistivity and magnetoresistivity for half-metallic ferromagnets,” Eur. Phys. J. B. 30, 481 (2002).
V. V. Marchenkov, N. I. Kourov, and V. Yu. Irkhin, “Half-metallic ferromagnets and spin gapless semiconductors,” Phys. Met. Metallogr. 119, 1321–1324 (2018).
V. V. Marchenkov, V. Yu. Irkhin, and Yu. A. Perevozchikova, “Peculiarities of electronic transport and magnetic state in half-metallic ferromagnetic and spin gapless semiconducting Heusler alloys,” Phys. Met. Metallogr. 120, 1325–1332 (2019).
H. Luo, Z. Zhu, L. Ma, S. Xu, X. Zhu, C. Jiang, H. Xu, and G. Wu, “Effect of site preference of 3d atoms on the electronic structure and half-metallicity of Heusler alloy Mn2 YAl,” J. Phys. D: Appl. Phys. 41, 055010 (2008).
C. B. Shoemaker, D. P. Shoemaker, T. E. Hopkins, and S. Yindepit, “Refinement of the structure of β-manganese and of a related phase in the Mn–Ni–Si system,” Acta Cryst. B. 34, 3573–3576 (1978).
P. Giannozzi, S. Baroni, N. Bonini, M. Calandra, R. Car, C. Cavazzoni, D. Ceresoli, G. L. Chiarotti, M. Cococcioni, I. Dabo, A. Dal Corso, S. de Gironcoli, S. Fabris, G. Fratesi, R. Gebauer, et al., “QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials,” J. Phys.: Condens. Matter. 21, 395502 (2009).
A. V. Sokolov, Optical Properties of Metals (Fizmatgiz, Moscow, 1961) [in Russian].
E. I. Shreder, A. D. Svyazhin, and A. A. Makhnev, “Evolution of the electronic structure and optical properties of iron-based Heusler alloys,” Opt. Spectrosc. 119, 969–973 (2015).
E. I. Shreder, A. A. Makhnev, A. V. Lukoyanov, and K. G. Suresh, “Electron structure and optical properties of the Heusler alloys Co2TiGe and Co2TiSn,” Phys. Met. Metallogr. 118, 965–969 (2017).
E. I. Shreder, A. A. Makhnev, A. V. Lukoyanov, and V. V. Marchenkov, “Electron structure and optical properties of the Mn1.8Co1.2Al alloy and spin gapless semiconductor state,” Phys. Met. Metallogr. 119, 1068–1072 (2018).
E. I. Shreder, M. M. Kirillova, and V. P. Dyakina, “Optical and electrical properties and electronic structure of Co2MnZ (Z = Al, Ga, Si, Sn, Sb),” Phys. Met. Metallogr. 81, 406–412 (1996).
E. I. Shreder, A. V. Lukoyanov, A. A. Makhnev, S. Dash, A. Patra, and M. Vasundhara, “Electronic structure and optical properties of the Mn2CrAl Heusler alloy,” Phys. Met. Metallogr. 121, 532–536 (2020).
C. N. Berglund and W. E. Spicer, “Photoemission studies of copper and silver: experiment,” Phys. Rev. A 136 (4), A1044–A1064 (1964).
Funding
This study was performed within the framework of State assignment from the Ministry of Education and Science of Russia (theme Electron, no. AAAA-A18-118020190098-5) and supported by the Russian Foundation for Basic Research and the Department of Science and Technology New Delhi, India within research project no. 19-52-45008_Ind-a-INT/RUS/RFBR/379, as well as by the Government of the Russian Federation (resolution no. 211, contract no. 02.A03.21.0006). Structural studies were performed in X-Ray Analysis Department of Collaborative Access Center “Testing Center of Nanotechnology and Advanced Materials” of the Institute of Metal Physics, Ural Branch, Russian Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Kadkin
Rights and permissions
About this article
Cite this article
Shreder, E.I., Makhnev, A.A., Lukoyanov, A.V. et al. Optical Properties of Heusler Alloy Mn2FeAl with the β-Mn Structure. Phys. Metals Metallogr. 122, 737–741 (2021). https://doi.org/10.1134/S0031918X21080147
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0031918X21080147