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Bimetallic Heterogeneous Catalysts for the Oxidation of Sulfur-Containing Compounds with Hydrogen Peroxide

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Abstract

Bimetallic heterogeneous catalysts based on SBA-15 containing molybdenum and iron oxides were studied in the oxidation reactions of model mixtures of organosulfur compounds. The addition of iron (in the form of iron(III) oxide) in an amount of 0.05 wt % to the catalyst 5% Mo/SBA-15 was the most effective. The catalysts were characterized by a complex of physicochemical methods: low-temperature adsorption–desorption of nitrogen, X-ray diffraction analysis, transmission electron microscopy, and X-ray photoelectron spectroscopy. The influence of the main oxidation parameters (reaction time, temperature, composition and amount of catalyst, and amount of oxidizing agent) on the conversion of dibenzothiophene as a component of the model mixture was investigated. Optimal oxidation conditions were selected to achieve the total conversion of the substrate: the molar ratio H2O2 : S = 2 : 1, 0.5 wt % FeMo/SBA-15 catalyst, 60 min, and 60°C. Catalysts can be used for at least five cycles without loss of activity during their intermediate washing from oxidation products.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    O. O. Gul, P. D. Polikarpova, A. V. Akopyan & A. V. Anisimov

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  1. O. O. Gul
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  2. P. D. Polikarpova
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Correspondence to O. O. Gul or P. D. Polikarpova.

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Translated by V. Makhlyarchuk

Abbreviations and notation: MeSPh, methyl phenyl sulfide; DBT, dibenzothiophene; BT, benzothiophene; 4-MDBT, 4‑methyldibenzothiophene; 4,6-DMDBT, 4,6-dimethyldibenzothiophene; BET, Brunauer–Emmett–Teller method; BJH, Barrett–Joyner–Halenda model; ATR, attenuated total reflectance; TEM, transmission electron microscopy; XRD, X-ray diffraction analysis; XPS, X-ray photoelectron spectroscopy; Ssp, specific surface area; Vpore, total pore volume; Dpore, pore diameter; Asp, specific activity.

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Gul, O.O., Polikarpova, P.D., Akopyan, A.V. et al. Bimetallic Heterogeneous Catalysts for the Oxidation of Sulfur-Containing Compounds with Hydrogen Peroxide. Kinet Catal 64, 627–634 (2023). https://doi.org/10.1134/S0023158423050038

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