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An XPS Study of the Interaction of NO2 with Sibunit in the Presence of Supported Palladium Particles

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Abstract

The interaction of NO2 with a carbon material from the Sibunit family with palladium metal particles supported on its surface was studied by X-ray photoelectron spectroscopy (XPS) at a pressure of 10–6 mbar in a temperature range from room temperature to 300°C. Two Pd/Sibunit samples, one of which was prepared by chemical deposition of palladium (Pd/C-HC sample) and the other, by vacuum evaporation of the metal onto the support (Pd/C-VE sample), were studied. Both of the samples showed similar behaviors in the interaction with NO2. Over the entire temperature range, the C1s spectrum of the samples contained a single peak with a binding energy of 284.4 eV from carbon atoms in the sp2-hybrid state, which indicated a weak effect of NO2 on Sibunit. At temperatures from room temperature to 150°C, the state of palladium supported onto the surface of Sibunit also did not change, but palladium was partially oxidized with the formation of PdO in a range from 200 to 300°C.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project no. AAAA-A21-121011390011-4). The studies were performed using the equipment of the Center of Collective Use National Center of Catalyst Research” (a SPECS X-ray photoelectron spectrometer and a JEM-2010 electron microscope).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. Yu. Smirnov, A. V. Kalinkin & V. I. Bukhtiyarov

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    P. A. Simonov

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  1. M. Yu. Smirnov
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  2. A. V. Kalinkin
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  3. P. A. Simonov
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Translated by V. Makhlyarchuk

Abbreviations and notation: XPS, X-ray photoelectron spectroscopy; Eb, binding energy; Ekin, kinetic energy; TEM, transmission electron microscopy; HOPG, highly oriented pyrolytic graphite.

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Smirnov, M.Y., Kalinkin, A.V., Simonov, P.A. et al. An XPS Study of the Interaction of NO2 with Sibunit in the Presence of Supported Palladium Particles. Kinet Catal 63, 532–542 (2022). https://doi.org/10.1134/S0023158422050111

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