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Formation of Surface Platinum Oxides in the Interaction of the Pt/Sibunit Catalysts with NO2: Estimates of the Width of Oxide Shell from XPS Data

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Abstract

The method of X-ray photoelectron spectroscopy (XPS) using two types of radiation, nonmonochromatic AlKα (hν = 1486.6 eV) and monochromatic AgLα (hν = 2984.3 eV), was used to study the interaction of the Pt/C (C = Sibunit) catalysts with NO2, which occurs in the preparation chamber of an XPS spectrometer at room temperature and NO2 pressure, equal to 3 × 10–6 mbar. It was found that, under these conditions, platinum was partially oxidized and metallic core becomes covered with a shell formed by a mixture of PtO and PtO2 oxides. The ratio of intensities Pt4f and Pt3d5/2 belonging to platinum oxides to the corresponding intensities of metallic platinum was used to estimate the width of oxide shell. For two of the three studied Pt/C samples, the width of the shell was 0.15–0.3 nm, which approximately corresponds to one monolayer of platinum oxide with a stoichiometry of PtO or PtO2.

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References

  1. Hendriksen, B.L.M. and Frenken, J.W.M., Phys. Rev. Lett., 2002, vol. 89, p. 046101.

    Article  CAS  PubMed  Google Scholar 

  2. Alayon, E.M.C., Singh, J., Nachtegaal, M., Harfouche, M., and van Bokhoven, J.A., J. Catal., 2009, vol. 263, p. 228.

    Article  CAS  Google Scholar 

  3. Singh, J., Nachtegaal, M., Alayon, E.M.C., Stötzel, J., and van Bokhoven, J.A., ChemCatChem, 2010, vol. 2, p. 653.

    Article  CAS  Google Scholar 

  4. Johánek, V., Václav, M., Matolínová, I., Khalakhan, I., Haviar, S., and Matolín, V., Appl. Surf. Sci., 2015, vol. 345, p. 319.

    Article  CAS  Google Scholar 

  5. Croy, J.R., Mostafa, S., Hickman, L., Heinrich, H., and Cuenya, B.R., Appl. Catal., A, 2008, vol. 350, p. 207.

    Article  CAS  Google Scholar 

  6. Lee, J.-H. and Kung, H.H., Catal. Lett., 1998, vol. 51, p. 1.

    Article  CAS  Google Scholar 

  7. Olsson, L. and Fridell, E., J. Catal., 2002, vol. 210, p. 340.

    Article  CAS  Google Scholar 

  8. Benard, S., Retailleau, L., Gaillard, F., Vernoux, P., and Giroir-Fendler, A., Appl. Catal., B, 2005, vol. 55, p. 11.

    Article  CAS  Google Scholar 

  9. Ono, L.K., Yuan, B., Heinrich, H., and Cuenya, B.R., J. Phys. Chem. C, 2010, vol. 114, p. 22119.

    Article  CAS  Google Scholar 

  10. Ono, L.K., Croy, J.R., Heinrich, H., and Cuenya, B.R., J. Phys. Chem. C, 2011, vol. 115, p. 16856.

    Article  CAS  Google Scholar 

  11. Hejral, U., Vlad, A., Nolte, P., and Stierle, A., J. Phys. Chem. C, 2013, vol. 117, p. 19955.

    Article  CAS  Google Scholar 

  12. Kalinkin, A.V., Sorokin, A.M., Smirnov, M.Yu., and Bukhtiyarov, V.I., Kinet. Catal., 2014, vol. 55, p. 354.

    Article  CAS  Google Scholar 

  13. Svintsitskiy, D.A., Kibis, L.S., Stadnichenko, A.I., Koscheev, S.V., Zaikovskii, V.I., and Boronin, A.I., ChemPhysChem, 2015, vol. 16, p. 3318.

    Article  CAS  PubMed  Google Scholar 

  14. Kalinkin, A.V., Smirnov, M.Y., and Bukhtiyarov, V.I., Kinet. Catal., 2016, vol. 57, p. 826.

    Article  CAS  Google Scholar 

  15. Ratnasamy, P., Leonard, A.J., Rodriquez, L., and Fripiat, J.J., J. Catal., 1973, vol. 29, p. 374.

    Article  CAS  Google Scholar 

  16. Yoshitoke, H., Yomozoki, O., and Oto, K., J. Electrochem. Soc., 1994, vol. 141, p. 2516.

    Article  Google Scholar 

  17. Wang, C.-B. and Yeh, C.-T., J. Catal., 1998, vol. 178, p. 450.

    Article  CAS  Google Scholar 

  18. Yoshida, H., Nonoyama, S., Yazawa, Y., and Hattori, T., Catal. Today, 2010, vol. 153, p. 156.

    Article  CAS  Google Scholar 

  19. Paredis, K., Ono, L.K., Mostafa, S., Li, L., Zhang, Z., Yang, J.C., Barrio, L., Frenkel, A.I., and Cuenya, B.R., J. Am. Chem. Soc., 2011, vol. 133, p. 6728.

    Article  CAS  PubMed  Google Scholar 

  20. Boubnov, A., Dahl, S., Johnson, E., Molina, A.P., Simonsen, S.B., Cano, F.M., Helveg, S., Lemus-Yegres, L.J., and Grunwaldt, J.-D., Appl. Catal., B, 2012, vol. 126, p. 315.

    Article  CAS  Google Scholar 

  21. Pakharukov, I.Y., Stakheev, A.Y., Beck, I.E., Zubavichus, Y.V., Murzin, V.Y., Parmon, V.N., and Bukhtiyarov, V.I., ACS Catal., 2015, vol. 2, p. 2795.

    Article  CAS  Google Scholar 

  22. Croy, J.R., Mostafa, S., Heinrich, H., and Cuenya, B.R., Catal. Lett., 2009, vol. 131, p. 21.

    Article  CAS  Google Scholar 

  23. Cuenya, B.R., Croy, J.R., Mostafa, S., Behafarid, F., Li, L., Zhang, Z., Yang, J.C., Wang, Q., and Frenkel, A.I., J. Am. Chem. Soc., 2010, vol. 132, p. 8747.

    Article  CAS  Google Scholar 

  24. Smirnov, M.Yu., Kalinkin, A.V., Vovk, E.I., and Bukhtiyarov, V.I., Kinet. Catal., 2015. vol. 56, p. 791.

    Google Scholar 

  25. Smirnov, M.Yu., Kalinkin, A.V., Vovk, E.I., Simonov, P.A., Gerasimov, E.Yu., Sorokin, A.M., and Bukhtiyarov, V.I., Appl. Surf. Sci., 2018, vol. 428, p. 972.

    Article  CAS  Google Scholar 

  26. Voropaev, I.N., Simonov, P.A., and Romanenko, A.V., Russ. J. Inorg. Chem., 2009, vol. 54, p. 1531.

    Article  Google Scholar 

  27. Mason, M.G., Phys. Rev. B, 1983, vol. 27, p. 748.

    Article  CAS  Google Scholar 

  28. Peuckert, M. and Bonzel, H.P., Surf. Sci., 1984, vol. 145, p. 239.

    Article  CAS  Google Scholar 

  29. Kaushik, V.K., Z. Phys. Chem., 1991, vol. 173, p. 105.

    Article  CAS  Google Scholar 

  30. Abe, Y., Yanagisawa, H., and Sasaki, K., Jpn. J. Appl. Phys., 1998, vol. 37, p. 4482.

    Article  CAS  Google Scholar 

  31. Pitchon, V. and Fritz, A., J. Catal., 1999, vol. 186, p. 64.

    Article  CAS  Google Scholar 

  32. Després, J., Elsener, M., Koebel, M., Kröcher, O., Schnyder, B., and Wokaun, A., Appl. Catal., B, 2004, vol. 50, p. 73.

    Article  CAS  Google Scholar 

  33. Kalinkin, A.V., Smirnov, M.Yu., Nizovskii, A.I., and Bukhtiyarov, V.I., J. Electron Spectrosc. Relat. Phenom., 2010, vol. 177, p. 15.

    Article  CAS  Google Scholar 

  34. Shinotsuka, H., Tanuma, S., Powell, C.J., and Penn, D.R., Surf. Interface Anal., 2015, vol. 47, p. 871.

    Article  CAS  Google Scholar 

  35. McBride, J.R., Graham, G.W., Peters, C.R., and Weber, W.H., J. Appl. Phys., 1991, vol. 69, p. 1596.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    M. Yu. Smirnov, E. I. Vovk, A. V. Kalinkin, P. A. Simonov, E. Yu. Gerasimov & V. I. Bukhtiyarov

  2. Novosibirsk State University, Novosibirsk, 630090, Russia

    V. I. Bukhtiyarov

Authors
  1. M. Yu. Smirnov
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  2. E. I. Vovk
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  3. A. V. Kalinkin
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  4. P. A. Simonov
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  5. E. Yu. Gerasimov
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  6. V. I. Bukhtiyarov
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Correspondence to M. Yu. Smirnov.

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Original Russian Text © M.Yu. Smirnov, E.I. Vovk, A.V. Kalinkin, P.A. Simonov, E.Yu. Gerasimov, V.I. Bukhtiyarov, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 5, pp. 642–651.

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Smirnov, M.Y., Vovk, E.I., Kalinkin, A.V. et al. Formation of Surface Platinum Oxides in the Interaction of the Pt/Sibunit Catalysts with NO2: Estimates of the Width of Oxide Shell from XPS Data. Kinet Catal 59, 663–671 (2018). https://doi.org/10.1134/S0023158418050130

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  • DOI: https://doi.org/10.1134/S0023158418050130

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