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Granulated Hierarchical Zeolite Y and Dealuminated Samples Based on It in Pentene Oligomerization

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Abstract

The catalytic properties of a number of FAU (Y) zeolite samples (microporous zeolite H-Y, granular hierarchical zeolite H-Yh, zeolite H-USYh dealuminated by high-temperature steam treatment (HTST), and zeolite H-USYh a.t. dealuminated by HTST with subsequent acid treatment) in the oligomerization of 1-pentene. The samples were characterized by X-ray fluorescence analysis, X-ray powder diffraction analysis, low-temperature nitrogen adsorption–desorption, scanning electron microscopy, and temperature-programmed desorption of ammonia. It was determined that the total yield of pentene oligomers under the studied conditions (150°С, 10 wt % catalyst, 5 h) decreases in the order H-USYh a.t. (93%) ≈ H-Yh (93%) > H-Y (74%) > H-USYh (70%). The dealuminated sample H-USYh a.t., which has the largest mesopore volume, showed high stability in 1-pentene oligomerization at 180°C. The conversion of the monomer in its presence remained unchanged during 5 cycles of operation without catalyst regeneration, and the yield of pentene oligomers after 5 cycles decreased by 39%. Microporous zeolite H-Y lost activity already after the second cycle.

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REFERENCES

  1. Cejka, J., Corma, A., and Zones, S. Zeolites and Catalysis: Synthesis, Reactions and Applications, Weinheim: Wiley, 2010.

    Book  Google Scholar 

  2. Kerstens, D., Smeyers, B., Van Waeyenberg, J., Qiang Zhang, Q., Yu, J., and Sels, B.S., Adv. Mater., 2020, vol. 32, no. 44., 2004 690.

    Article  Google Scholar 

  3. Chen, L.-H., Sun, M.-H., Wang, Zh., Yang, W., Xie, Z., and Su, B.-L., Chem. Rev., 2020, vol. 120, vol., 20, p. 11194.

  4. Corma, A., Martínez, C., and Doskocil, E., J. Catal., 2013, vol. 300, p. 183.

    Article  CAS  Google Scholar 

  5. Zhang, L., Ke, M., Song, Z., Liu, Ya., Shan, W., Wang, Q., Xia, Ch., Li, Ch., and He, Ch., Catalysts, 2018, vol. 8, no. 8, p. 298.

    Article  Google Scholar 

  6. Moon, S., Chae, H.J., and Park, M.B., Appl. Catal., A, 2018, vol. 553, p. 15.

  7. Monama, W., Mohiuddin, E., Thangaraj, B., Mdleleni, M.M., and Key, D., Catal. Today, 2020, vol. 342, p. 167.

    Article  CAS  Google Scholar 

  8. Chal, R., Gérardin, C., Bulut, M., and van Donk, S., Chem. Cat. Chem., 2011, vol. 3, p. 67.

    CAS  Google Scholar 

  9. Wei, Y., Parmentier, T.E., de Jong, P.K., and Zečević, J., Chem. Soc. Rev., 2015, vol. 44, p. 7234

    Article  CAS  Google Scholar 

  10. Feliczak-Guzik, A., Microporous Mesoporous Mater., 2017, vol. 259, p. 33.

    Article  Google Scholar 

  11. Jia, X., Khan, W., Wu, Z., Choi, J., and Yip, A.C.K., Adv. Powder Technol., 2019, vol. 30, p. 467.

    Article  CAS  Google Scholar 

  12. Patent RF No. 2456238, 2012.

  13. Patent RF No. 2739350, 2020.

  14. Kutepov, B.I., Travkina, O.S., Agliullin, M.R., Khazipova, A.N., Pavlova, I.N., Bubennov, S.V., Kostyleva, S.A., and Grigor’eva, N.G., Pet. Chem., 2019, vol. 59, p. 297.

    Article  CAS  Google Scholar 

  15. Travkina, O.S., Agliullin, M.R., Filippova, N.A., Khazipova, A.N., Danilova, I.G., Grigor’eva, N.G., Narender, N., Pavlov, M.L., and Kutepov, B.I., RSC Adv., 2017, vol. 7. P. 32581.

    Article  CAS  Google Scholar 

  16. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.

    Google Scholar 

  17. Silaghi, M.-Ch., Chizallet, C., and Raybaud, P., Microporous Mesoporous Mater, 2014, vol. 191, p. 82.

    Article  CAS  Google Scholar 

  18. van Donk, S., Broersma, A., Gijzeman, O.L.J., van Bokhoven, J.A., Bitter, J.H., and de Jong, K.P., J. Catal., 2001, vol. 204, p. 272.

    Article  CAS  Google Scholar 

  19. Verboekend, D., Chabaneix, A.M., Thomas, K., Gilson, J.-P., and Pérez-Ramírez, J., CrystEngComm, 2011, vol. 13, p. 3408.

    Article  CAS  Google Scholar 

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Funding

This work was performed under state assignment for the Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, Russia (subject no. FMRS-2022-0080). The study of the synthesis of pentene oligomers was supported by the Russian Foundation for Basic Research (project no. 20-33-90120). The structural studies were carried out at the Agidel’ Regional Center for Shared Equipment Use, Ufa Federal Research Center, Russian Academy of Sciences, under state assignment for the Institute of Petrochemistry and Catalysis (subject no. FMRS-2022-0081).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    D. V. Serebrennikov, N. G. Grigor’eva, A. N. Khazipova & B. I. Kutepov

  2. Ufa State Petrochemical Technical University, 450062, Ufa, Russia

    Z. S. Samigullina

Authors
  1. D. V. Serebrennikov
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  2. N. G. Grigor’eva
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  3. A. N. Khazipova
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  4. Z. S. Samigullina
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  5. B. I. Kutepov
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Corresponding authors

Correspondence to D. V. Serebrennikov or N. G. Grigor’eva.

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The authors declare that they have no conflicts of interest.

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Translated by V. Glyanchenko

Abbreviations and notation: HTST, high-temperature heat treatment; DC, degree of crystallinity; XRD, X-ray powder diffraction analysis.

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Serebrennikov, D.V., Grigor’eva, N.G., Khazipova, A.N. et al. Granulated Hierarchical Zeolite Y and Dealuminated Samples Based on It in Pentene Oligomerization. Kinet Catal 63, 577–584 (2022). https://doi.org/10.1134/S0023158422050093

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  • DOI: https://doi.org/10.1134/S0023158422050093

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