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Formation of Effective Copper-Based Catalysts of Methanol Synthesis

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Abstract

The regularities of formation of the composition and structure of a highly efficient catalyst for methanol synthesis have been revealed. The catalyst was obtained by thermal treatment of the combined CuZnAl(Cr) hydroxocarbonate followed by the reductive activation of the anion-modified zinc oxide precursor. The composition and structure of hydroxocarbonate are determined by the nature of components and their ratio. The thermal decomposition of hydroxocarbonates at 550–650 K formed the oxide catalyst; at higher temperatures, the product was an inactive mixture of oxides. The oxide catalyst is mixed zinc oxide containing the Cu2+ and Al or Cr3+ cations and residual (СО3)2– and ОН– anions, i.e., the anion-modified oxide.

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ACKNOWLEDGMENTS

We are grateful to M.P. Demeshkina for sample preparation, to N.V. Shtertser for DTA studies, to I.Yu. Molina for XRD studies, and to Prof. L.M. Plyasova for useful discussions.

Funding

This study was performed under government contract at the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. АААА-А17-117041110045-9).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    T. P. Minyukova, A. A. Khassin, A. V. Khasin & T. M. Yurieva

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  1. T. P. Minyukova
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  2. A. A. Khassin
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  3. A. V. Khasin
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  4. T. M. Yurieva
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Correspondence to T. P. Minyukova.

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Translated by L. Smolina

Abbreviations and notation: DTA, differential thermal analysis; XRD, X-ray diffraction analysis; EM, electron microscopy; EXAFS, extended X-ray absorption fine structure; UV–Vis, spectroscopy in the UV and visible regions; HT-CO3, high-temperature carbonates.

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Minyukova, T.P., Khassin, A.A., Khasin, A.V. et al. Formation of Effective Copper-Based Catalysts of Methanol Synthesis. Kinet Catal 61, 886–893 (2020). https://doi.org/10.1134/S0023158420060087

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