Skip to main content
SpringerLink
Log in

Effect of Zr Content on the Activity of 5%СuO/Ce1– xZrxO2 Catalysts in CO Oxidation by Oxygen in the Excess of Hydrogen

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The article reports the synthesis of 5%CuO/Ce1– xZrxO2 catalysts based on CeO2, ZrO2 oxides and Ce1– xZrxO2 solid solutions with х = 0.2, 0.5, and 0.8. It is found that copper oxide is present in the catalysts in a highly dispersed form. In strong interaction with supports, it forms active oxygen, which participates in CO chemisorption and low-temperature oxidation of CO in the presence of hydrogen. In selective CO oxidation, the highest conversion (γmах = 100%) was obtained at temperatures of 120–160°С in the presence of 5%CuO/CeO2. In the modification of CeO2 by zirconium cations, the conversion on 5%Ce0.5Zr0.5O2 decreases to 92% at 160°С because oxygen binding strengthens on copper-containing sites. On the 5%CuO/ZrO2 sample, the maximum conversion is 67% at 180°С. The modification of ZrO2 by cerium cations leads to an increase in the conversion to 87% at 160°С on the 5%CuO/Ce0.2Zr0.8O2 sample as a result of increasing the amount of oxygen vacancies in the support. Taking into account the properties of CO complexes formed on copper-containing oxidation and adsorption sites, and the interaction of these complexes with adsorbed oxygen, their participation in the reaction of low-temperature CO oxidation by oxygen in excess of hydrogen on 5%CuO/CeO2 and 5%CuO/ZrO2 catalysts is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. Mishra, A. and Prasad, R., Bull. Chem. React. Eng. Catal., 2011, vol. 6, no. 1, p. 1.

    Article  CAS  Google Scholar 

  2. Olah, D., Goeppert, A., and Surya Prokash, G.K., Beyond Oil and Gas: The Methanol Economy, Weinheim: Wiley, 2009.

    Book  Google Scholar 

  3. Avgouropoulos, G. and Ioannides, T., Appl. Catal., A, 2003, vol. 244, p. 155.

  4. Martinez-Arias, A., Gamarra, D., Hungria, A.B., Fernandez-Garcia, M., Munuera, G., Hornes, A., Bera, P., Conesa, J.C., and Camara, A.L., Catalysts, 2013, vol. 3, p. 378.

    Article  CAS  Google Scholar 

  5. Firsova, A.A., Il’ichev, A.N., Khomenko, T.I., Gorobinskii, L.V., Maksimov, Yu.V., Suzdalev, I.P., and Korchak, V.N., Kinet. Catal., 2007, vol. 48, no. 2, p. 282.

    Article  CAS  Google Scholar 

  6. Balducci, G., Islam, M.S., Kaspar, J., Fornasiero, P., and Graziani, M., Chem. Mater., 2003, vol. 15, p. 3781.

    Article  Google Scholar 

  7. Kaspar, J., Fornasiero, P., and Hickey, N., Catal. Today, 2003, vol. 77, p. 419.

    Article  CAS  Google Scholar 

  8. Cao, J.-L., Wang, Y., Zhang, T.-Y., Wu, S.-H., and Yuan, Z.-Y., Appl. Catal., B, 2008, vol. 78, p. 120.

    Article  CAS  Google Scholar 

  9. Manzoli, M., Monte, R.D., Boccuzzi, F., Coluccia, S., and Kaspar, J., Appl. Catal., B, 2005, vol. 61, p. 192.

    Article  CAS  Google Scholar 

  10. Ratnasamy, P., Strinivas, D., Satyanarayana, C.V.V., Manikandan, P., Kumaran, R.S.S., Sachin, M., and Shetti, V.N., J. Catal., 2004, vol. 221, p. 455.

    Article  CAS  Google Scholar 

  11. Martinez-Arias, A., Fernandez-Garcia, M. Galvez, O., Coronado, J.M., Anderson, J.A., Conesa, J.C., Soria, J., and Munuera, G., J. Catal., 2000, vol. 195, p. 207.

    Article  CAS  Google Scholar 

  12. Il’ichev, A.N., Firsova, A.A., and Korchak, V.N., Kinet. Catal., 2006, vol. 47, no. 4, p. 585.

    Article  Google Scholar 

  13. Il’ichev, A.N., Bykhovskii, M.Ya., Fattakhova, Z.T., Shashkin, D.P., Matyshak, V.A., and Korchak, V.N., Kinet. Catal., 2018, vol. 59, no. 2, p. 179.

    Article  Google Scholar 

  14. Firsova, A.A, Khomenko, T.I., Il’ichev, A.N., and Korchak, V.N., Kinet. Catal., 2011, vol. 52, no. 3, p. 434.

    Article  CAS  Google Scholar 

  15. Sadykov, V.A., Simonov, M.N., Mezentseva, N.V., Pavlova, S.N., Fedorova, Y.E., Bobin, A.S., Bespalko, Y.N., Ishchenko, A.V., Krieger, T.A., Glazneva, T.S., Larina, T.V., Cherepanova, S.V., Kaichev, V.V., Saraev, A.A., Chesalov, Y., Shmakov, A.N., Roger, A.-C., and Adamski, A., Open Chem., 2016, vol. 14, p. 363.

    Article  CAS  Google Scholar 

  16. Powder Diffraction Fale. Alphabetical Indoxos. Inorganic phases, JCPDS, Pennsylvania: International Center for Diffraction Data, 1983.

  17. Mirkin, L.I., Spravochnik po rentgenostrukturnomu analizu polikristallov (Polycrystalls X-ray Diffraction Handbook), Moscow: Gos. Izd. Fiz.-Mat. Lit., 1961.

  18. Tret'yakov, I.I., Shub, B.R., and Sklyarov, A.V., Zh. Fiz. Khim., 1970, vol. 44, p. 2112.

    CAS  Google Scholar 

  19. Handbuch der Präparativen Anorganischen Chemie. Brauer, G., 1962, Stuttgart: Ferdinand Enke-Verlag.

  20. Rodriguez, J.A. Hanson, J.C. Kim, J.-Y. Liu, G., Iglesias-Juez, A., and Fernandez-Garcia, M., J. Phys. Chem. B, 2003, vol. 107, p. 3535.

    Article  CAS  Google Scholar 

  21. Narula, C.K., Haack, L.P., Chun, W., Jen, H.-W., and Graham, G.W., J. Phys. Chem. B, 1999, vol. 103, p. 3634.

    Article  CAS  Google Scholar 

  22. Trovarelli, A., Zamar, F., Llorca, J., Leitenburg, C., Dolcetti, G., and Kiss, J.T., J. Catal., 1997, vol. 169, p. 490.

    Article  CAS  Google Scholar 

  23. Fornasiero, P., Balducci, G., Monte, R.D., Kaspar, J., Sergo, V., Gubitosa, G., Ferrero, A., and Graziani, M., J. Catal., 1996, vol. 164, p. 173.

    Article  CAS  Google Scholar 

  24. Fully, F., Perrichon, V., Vidal, H., Kaspar, J., Blanco, G., Pintado, J.M., Bernal, S., Golon, G., Daturi, M., and Lavalley, J.C., Catal. Today, 2000, vol. 59, p. 373.

    Article  Google Scholar 

  25. Maity, S.K., Rana, M.S., Srinavas, B.N., Bej, S.K., Dhar, G.M., and Prasada Rao, T.S.R., J. Mol. Catal. A: Chem., 2000, vol. 153, p. 121.

    Article  CAS  Google Scholar 

  26. Il’ichev, A.N., Matyshak, V.A., and Korchak, V.N., Kinet. Catal., 2015, vol. 56, no. 1, p. 115.

    Article  Google Scholar 

  27. Il’ichev, A.N., Shashkin, D.P., Matyshak, V.A., and Korchak, V.N., Kinet. Catal., 2015, vol. 56, no. 2, p. 197.

    Article  Google Scholar 

  28. Luo, M.F., Ma, J.-M., Lu, J.-Q., Song, Y.-P., and Wang, Y.-J., J. Catal., 2007, vol. 246, p. 52

    Article  CAS  Google Scholar 

  29. Gomez-Cortes, A., Marquez, Y., Arenas-Alatorre, J., and Diaz, G., Catal. Today, 2008, vols. 133–135, p. 743.

    Article  Google Scholar 

  30. Polster, C.S., Naier, H., and Baertsch, C.D., J. Catal., 2009, vol. 266, p. 308.

    Article  CAS  Google Scholar 

  31. Moretti, E., Storaro, L., Talon, A., Lenarda, M., Riello, P., Frattini, R., Yuso, M.V.M., Jimenez-Lopez, A., Rodriguez-Gastellon, E., Ternero, F., Caballero, A., and Holgado, J.P., Appl. Catal., B, 2011, vol. 102, p. 627.

    Article  CAS  Google Scholar 

  32. Arango-Diaz, A., Cecilia, J.A., Moretti, E., Talon, A., Nunez, P., Morrero-Jerez, J., Jimenez-Jimenez, J., Jimenez-Lopez, A., and Rodriguez-Gastellon, E., Int. J. Hydrogen Energy, 2014, vol. 39, p. 4102.

    Article  CAS  Google Scholar 

  33. Wang, S.-P., Zheng, X.-C., Wang, X.-Y., Wang, S.-R., Zhang, S.-M., Yu, L.-H., Huang, W.-P., and Wu, S.-H., Catal. Lett., 2005, vol. 105, nos. 3–4, p. 163.

    Article  CAS  Google Scholar 

  34. Dow, W.-P. and Huang, T.-J., J. Catal., 1996, vol. 160, p. 171.

    Article  CAS  Google Scholar 

  35. Dow, W.-P., Wang, Y.P., and Huang, T.-J., Appl. Catal., A, 2000, vol. 190, p. 25.

  36. Il’ichev, A.N., Shashkin, D.P., Khomenko, T.I., Fattakhova, Z.T., and Korchak, V.N., Kinet. Catal., 2010, vol. 51, no. 5, p. 743.

    Article  Google Scholar 

  37. Dow, W.-P., Wang, Y.P., and Huang, T.-J., J. Catal., 1996, vol. 160, p. 155.

    Article  CAS  Google Scholar 

  38. Krylov, O.V., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Akademkniga, 2004.

Download references

Funding

This work was supported by grant no. 18-03-00627 A from the Russian Foundation for Basic Research and was carried out as part of the state assignment of the FASO Russia (theme V.46. 13, 0082-2014-0007, registration no. AAAA-A18-118020890105-3).

Author information

Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    A. N. Il’ichev, M. Ya. Bykhovsky, Z. T. Fattakhova, D. P. Shashkin, V. A. Matyshak & V. N. Korchak

  2. Boreskov Institute of Catalysis, Siberian Branch, 630090, Novosibirsk, Russia

    Yu. E. Fedorova

Authors
  1. A. N. Il’ichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Ya. Bykhovsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Z. T. Fattakhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. P. Shashkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. E. Fedorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. A. Matyshak
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. N. Korchak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Il’ichev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Il’ichev, A.N., Bykhovsky, M.Y., Fattakhova, Z.T. et al. Effect of Zr Content on the Activity of 5%СuO/Ce1– xZrxO2 Catalysts in CO Oxidation by Oxygen in the Excess of Hydrogen. Kinet Catal 60, 661–671 (2019). https://doi.org/10.1134/S002315841905001X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002315841905001X

Keywords:

Search

Navigation