Skip to main content
SpringerLink
Log in

One-pot solvothermal synthesis of hypercrosslinked porous ionic polymer and its catalytic activity

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The hypercrosslinked porous ionic polymer has been synthesized via one-pot polymerization and quaternization of vinyl pyridine and chloromethyl styrene under solvothermal condition. The effects of solvents and synthetic process on the polymer structure were investigated. Polymer from n-butanol showed the highest BET surface area of 555.6 m2/g. The catalytic activities were investigated though the aza-Michael addition and the results showed that the polymer owned even higher activity than homogenous ionic liquid. The high BET surface area, high catalytic activity and high stability made the polymer hold great potential for green chemical processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Greaves, T.L. and Drummond, C.J., Chem. Rev., 2008, vol. 108, p. 206.

    Article  CAS  Google Scholar 

  2. Wasserscheid, P. and Keim, W., Angew. Chem., Int. Ed. Engl., 2000, vol. 112, p. 3926.

    Article  Google Scholar 

  3. Sheldon, R., Chem. Commun., 2001, p. 2399.

    Google Scholar 

  4. Zhao, D., Wu, M., Kou, Y., and Min, E., Catal. Today, 2002, vol. 74, p. 157.

    Article  CAS  Google Scholar 

  5. Dupont, J., de Souza, R.F., and Suarez, P.A.Z., Chem. Rev., 2002, vol. 102, p. 3667.

    Article  CAS  Google Scholar 

  6. Li, J., Shi, X.Y., Bi, Y.Y., Wei, J.F., and Chen, Z.G., ACS Catal., 2011, vol. 1, p. 657.

    Article  CAS  Google Scholar 

  7. Yamaguchi, K., Yoshida, C., Uchida, S., and Mizuno, N.P., J. Am. Chem. Soc., 2005, vol. 127, p. 530.

    Article  CAS  Google Scholar 

  8. Amarasekara, A.S. and Owereh, O.S., Catal. Commun., 2010, vol. 11, p. 1072.

    Article  CAS  Google Scholar 

  9. Agrigento, P., Al-Amsyar, S.M., Soree, B., Taherimehr, M., Gruttadauria, M., Aprile, C., and Pescarmona, P.P., Catal. Sci. Technol., 2014, vol. 4, p. 1598.

    Article  CAS  Google Scholar 

  10. Rostamnia, S., Hassankhani, A., Hossieni, H.G., Gholipour, B., and Xin, H., J. Mol. Catal. A: Chem., 2014, vol. 395, p. 463.

    Article  CAS  Google Scholar 

  11. Wang, B., Zhang, J., Zou, X., Dong, H., and Ya, P., Chem. Eng. J., 2015, vol. 260, p. 172.

    Article  CAS  Google Scholar 

  12. Karimi, B., Elhamifar, D., Clark, J.H., and Hunt, A.J., Chem. Eur. J., 2010, vol. 16, p. 8047.

    Article  CAS  Google Scholar 

  13. Xie, Y., Zhang, Z., Jiang, T., He, J., Han, B., Wu, T., and Ding, K., Angew. Chem., Int. Ed. Engl., 2007, vol. 46, p. 7255.

    Article  CAS  Google Scholar 

  14. Zhang, Y., Wei, S., Liu, F., Dua, Y., Liu, S., Ji, Y., Yokoi, T., Tatsumi, T., and Xiao, F.-S., Nano Today, 2009, vol. 4, p. 135.

    Article  CAS  Google Scholar 

  15. Liu, F., Wang, L., Sun, Q., Zhu, L., Meng, X., and Xiao, F.-S., J. Am. Chem. Soc., 2012, vol. 134, p. 16948.

    Article  CAS  Google Scholar 

  16. Liang, X., Xiao, H., and Qi, C., Fuel Process. Technol., 2013, vol. 110, p. 109.

    Article  CAS  Google Scholar 

  17. Li, J., Lu, W., Li, W., and Liang, X., Kinet. Catal., 2016, vol. 57, p. 840.

    Article  CAS  Google Scholar 

  18. Tsyurupa, M.P. and Davankov, V.A., React. Funct. Polym., 2002, vol. 53, p. 193.

    Article  CAS  Google Scholar 

  19. Zhang, Y., Wei, S., Liu, F., Du, Y., Liu, S., Ji, Y., Yokoi, T., Tatsumi, T., and Xiao, F.-S., Nano Today, 2009, vol. 4, p. 135.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, 312000, China

    Jiahui Xie, Mengjia Wang, Ying Wang, Qingbao Zhuang & Xuezheng Liang

Authors
  1. Jiahui Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mengjia Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ying Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qingbao Zhuang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xuezheng Liang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xuezheng Liang.

Additional information

Published in Russian in Kinetika i Kataliz, 2017, Vol. 58, No. 3, pp. 338–344.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xie, J., Wang, M., Wang, Y. et al. One-pot solvothermal synthesis of hypercrosslinked porous ionic polymer and its catalytic activity. Kinet Catal 58, 321–327 (2017). https://doi.org/10.1134/S0023158417030119

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158417030119

Keywords

Search

Navigation