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Synthesis of Novel Ionic Porous Organic Polymers and Its Application in Hydroxyl Condensation Reaction

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Abstract

A novel ionic porous organic polymers catalysts were prepared and characterized by scanning electron microscopy, Brunner − Emmet − Teller measurements, fourier transform infrared spectroscopy and thermogravimetric analysis The characterization results showed that the synthesized catalyst was a porous polymer and had good heat stability. The catalytic performance of the catalyst was evaluated by synthesis of methacrolein from formaldehyde and propionaldehyde. The optimal reaction conditions were: the catalyst amount was 10%(wt%)of propionic aldehyde mass, the reaction temperature was 85 ℃, the reaction time was 1.5 h, the ratio of propionaldehyde and formaldehyde was 1:1.2. Under optimal condition, the conversion rate of propionaldehyde was up to 99.57% and the selectivity of methacrolein was 98.77%. The catalytic activity did not reduced obviously after being reused for 5 times. The reaction kinetics of synthesis of methacrolein was further studied. The results showed that the reaction order was 1.6, the activation energy was 50.28 kJ/mol and the pre-exponential factor was 4.17 × 107 (mol/L)−1.456/s.

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Acknowledgements

This research was supported by the national natural science foundation of China (NO. 21106032), natural science foundation of Hebei province (NO. B2021103012).

Funding

Natural Science Foundation of Hebei Province,NO. B2021103012, National Natural Science Foundation of China, NO. 21106032

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Authors and Affiliations

  1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, 26 Yuxiang Street, Shijiazhuang, 050018, China

    Yajuan Wang, Wenqiang Liu, Juan Zhang & Qingwen Shan

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  1. Yajuan Wang
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  2. Wenqiang Liu
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Correspondence to Juan Zhang.

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Wang, Y., Liu, W., Zhang, J. et al. Synthesis of Novel Ionic Porous Organic Polymers and Its Application in Hydroxyl Condensation Reaction. Catal Lett 153, 1797–1806 (2023). https://doi.org/10.1007/s10562-022-04110-3

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