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Catalytic activity of iron hydroxides and manganese hydroxides in the deoxygenation of water

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Abstract

Catalysts prepared by the modification of FIBAN K-4 and FIBAN X-1 fibrous ion exchangers with the hydroxides of iron and manganese were developed and tested in a water deoxygenation process. It was established that the samples obtained by the supporting of Fe(III) hydroxide onto the FIBAN X-1 ampholyte were most effective. The conclusion that the high activity of the catalytic system is caused by the formation of a mixed phase of Fe(II) and Fe(III) hydroxides of the spinel type containing mobile (weakly bound) lattice oxygen was made. A reaction scheme was proposed to explain the reaction mechanism.

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, Belarussian Academy of Sciences, Minsk, 220072, Belarus

    Yu. G. Egiazarov, A. Yu. Volodin, L. L. Potapova & B. Kh. Cherches

Authors
  1. Yu. G. Egiazarov
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  2. A. Yu. Volodin
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  3. L. L. Potapova
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  4. B. Kh. Cherches
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Corresponding author

Correspondence to Yu. G. Egiazarov.

Additional information

Original Russian Text © Yu.G. Egiazarov, A.Yu. Volodin, L.L. Potapova, B.Kh. Cherches, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 3, pp. 274–282.

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Egiazarov, Y.G., Volodin, A.Y., Potapova, L.L. et al. Catalytic activity of iron hydroxides and manganese hydroxides in the deoxygenation of water. Kinet Catal 58, 262–270 (2017). https://doi.org/10.1134/S0023158417030065

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  • DOI: https://doi.org/10.1134/S0023158417030065

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