Abstract
The formation of Ag–Au, Cu–Au, and Ag–Cu bimetallic particles on the surface of highly oriented pyrolytic graphite was studied by X-ray photoelectron spectroscopy. Samples with the core–shell structure of particles were prepared by sequential thermal vacuum deposition. The thermal stability of the samples was studied over a wide range of temperatures (25-400°C) under ultrahigh-vacuum conditions. The heating of the samples to ~250°C leads to the formation of bimetallic alloy particles with a relatively uniform distribution of metals in the bulk. The thermal stability of the samples with respect to sintering depends on the nature of the supported metals. Thus, the Ag–Au particles exhibited the highest thermal resistance (~350°C) under ultrahigh-vacuum conditions, whereas the Ag–Cu particles agglomerated even at ~250°C.
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Wang, A., Liu, X.Y., Mou, C.-Y., and Zhang, T., J. Catal., 2013, vol. 308, p. 258.
Bukhtiyarov, V.I. and Slin’ko, M.G., Russ. Chem. Rev., 2001, vol. 70, p. 147.
Ananikov, V.P., Khemchyan, L.L., Ivanova, Yu.V., Bukhtiyarov, V.I., Sorokin, A.M., Prosvirin, I.P., Vatsadze, S.Z., Medved’ko, A.V., Nuriev, V.N., Dil’man, A.D., Levin, V.V., Koptyug, I.V., Kovtunov, K.V., Zhivonitko, V.V., Likholobov, V.A., et al., Russ. Chem. Rev., 2014, vol. 83, p. 885.
Jiang, H.-L. and Xu, Q., J. Mater. Chem., 2011, vol. 21, p. 13705.
Tao, F., Zhang, S., Nguyen, L., and Zhang, X., Chem. Soc. Rev., 2012, vol. 41, p. 7980.
Tao, F., Grass, M.E., Zhang, Y., Butcher, D.R., Renzas, J.R., Liu, Z., Chung, J.Y., Mun, B.S., Salmeron, M., and Somorjai, G.A., Science, 2008, vol. 322, p. 932.
Gao, F. and Goodman, D.W., Chem. Soc. Rev., 2012, vol. 41, p. 8009.
Ellert, O.G., Tsodikov, M.V., Nikolaev, S.A., and Novotortsev, V.M., Russ. Chem. Rev., 2014, vol. 83, p. 718.
Chen, M.S., Kumar, D., Yi, C.-W., and Goodman, D.W., Science, 2005, vol. 310, p. 291.
Pritchard, J.C., He, Q., Ntainjua, E.N., Piccinini, M., Edwards, J.K., Herzing, A.A., Carley, A.F., Moulijn, J.A., Kiely, C.J., and Hutchings, G., Green Chem., 2010, vol. 12, p. 915.
Liao, X.M., Caps, V., Chu, W., and Pitchon, V., RSC Adv., 2016, vol. 6, p. 4899.
Liua, X., Wanga, A., Lia, L., Zhang, T., Mou, Ch.-Y., and Lee, J.-F., Prog. Nat. Sci. Mater. Int., 2013, vol. 23, p. 317.
Li, W., Wang, A., Liu, X., and Zhang, T., Appl. Catal., A, 2012, vol. 433-434, p. 146.
Fiorenza, R., Crisafulli, C., Condorelli, G.G., Lupo, F., and Scire, S., Catal. Lett., 2015, vol. 145, p. 1691.
Llorca, J., Dominguez, M., Ledesma, C., Chimentao, R., Medina, F., Sueiras, J., Angurell, I., Seco, M., and Rossell, O., J. Catal., 2008, vol. 258, p. 187.
Ponec, V., Appl. Catal., A, 2001, vol. 222, p. 31.
Liu, P. and Norskov, J.K., Phys. Chem. Chem. Phys., 2001, vol. 3, p. 3814.
Xu, J., White, T., Li, P., He, C.H., Yu, J.G., Yuan, W.K., and Han, Y.F., J. Am. Chem. Soc., 2010, vol. 132, p. 10398.
Gao, F., Wang, Y.L., and Goodman, D.W., J. Am. Chem. Soc., 2009, vol. 131, p. 5734.
Bukhtiyarov, A.V., Kvon, R.I., Nartova, A.V., and Bukhtiyarov, V.I., Russ. Chem. Bull., 2011, vol. 60, p. 1977.
Demidov, D.V., Prosvirin, I.P., Sorokin, A.M., Rosha, T., Knop-Gerike, A., and Bukhtiyarov, V.I., Kinet. Catal., 2011, vol. 52, p. 855.
Kalinkin, A.V., Smirnov, M.Yu., Bukhtiyarov, A.V., and Bukhtiyarov, V.I., Kinet. Catal., 2015, vol. 56, p. 796.
Bukhtiyarov, A.V., Nartova, A.V., and Kvon, R.I., Kinet. Catal., 2011, vol. 52, p. 756.
Bukhtiyarov, A.V., Prosvirin, I.P., and Bukhtiyarov, V.I., Appl. Surf. Sci., 2016, vol. 367, p. 214.
http://www.bessy.de/rglab/index.html
Tanuma, S., Powell, C.J., and Penn, D.R., Surf. Interface Anal., 1993, vol. 21, p. 165.
Practical Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy, Briggs, D. and Seah, M.P., Eds., Chichester, UK: Wiley, 1983.
Moulder, J.F., Stickle, W.F., Sobol, P.E., and Bomben, K.D., Handbook of X-Ray Photoelectron Spectroscopy, Chastain J., King R.C., Jr., Eds., Eden Prairie, Minn.: Perkin Elmer, 1992.
Yeh, J.-J. and Lindau, I., At. Data Nucl. Data Tables, 1985, vol. 32, p. 1.
http://www.quases.com/products/quases-imfp-tpp2m/
http://xpspeak.software.informer.com/4.1/
Demidov, D.V., Prosvirin, I.P., Sorokin, A.M., and Bukhtiyarov, V.I., Catal. Sci. Technol., 2011, vol. 1, p. 1432.
Yang, D.-Q., Zhang, G.-Z., Sacher, E., Jose-Yacaman, M., and Elizondo, N., J. Phys. Chem. B, 2006, vol. 110, p. 8348.
Ono, L.K., Sudfeld, D., and Roldan Cuenya, B., Surf. Sci., 2006, vol. 600, p. 5041.
Schmid, M., Madix, R.J., and Friend, C.M., Surf. Sci., 2016, vol. 643, p. 36.
Yi, C.W., Luo, K., Wei, T., and Goodman, D.W., J. Phys. Chem. B, 2005, vol. 109, p. 18535.
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Original Russian Text © A.V. Bukhtiyarov, I.P. Prosvirin, I.A. Chetyrin, A.A. Saraev, V.V. Kaichev, V.I. Bukhtiyarov, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 5, pp. 711–718.
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Bukhtiyarov, A.V., Prosvirin, I.P., Chetyrin, I.A. et al. Thermal stability of Ag–Au, Cu–Au, and Ag–Cu bimetallic nanoparticles supported on highly oriented pyrolytic graphite. Kinet Catal 57, 704–711 (2016). https://doi.org/10.1134/S0023158416050049
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DOI: https://doi.org/10.1134/S0023158416050049