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Crystal Structure of DL-Serinium Heptafluorodiantimonate(III)

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Abstract

The crystal structure of DL-serinium heptafluorodiantimonate(III) (C3H8NO3)Sb2F7 (I) synthesized for the first time is determined (monoclinic crystal system: a = 6.6367(1) Å, b = 5.9521(1) Å, c = 13.5562(3) Å, Z = 2, space group P21). The structure of (C3H8NO3)Sb2F7 represents a new structure type of complex antimony(III) fluoride with a protonated amino acid cation. It is formed of DL-serinium (C3H8NO3)+ cations and dimeric [Sb2F7]- anion complexes. The complex [Sb2F7]- anions consist of two trigonal SbF4E bipyramids sharing a vertex. The structural units are arranged into a three-dimensional framework via N–H⋯F, O–H⋯O, and O–H⋯F hydrogen bonds.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    A. A. Udovenko, N. V. Makarenko, E. V. Kovaleva & L. A. Zemnukhova

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  1. A. A. Udovenko
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  2. N. V. Makarenko
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  3. E. V. Kovaleva
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  4. L. A. Zemnukhova
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Corresponding author

Correspondence to A. A. Udovenko.

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Original Russian Text © 2018 A. A. Udovenko, N. V. Makarenko, E. V. Kovaleva, L. A. Zemnukhova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 6, pp. 1474–1479, July-August, 2018.

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Udovenko, A.A., Makarenko, N.V., Kovaleva, E.V. et al. Crystal Structure of DL-Serinium Heptafluorodiantimonate(III). J Struct Chem 59, 1421–1426 (2018). https://doi.org/10.1134/S0022476618060240

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  • DOI: https://doi.org/10.1134/S0022476618060240

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