Skip to main content
SpringerLink
Log in

Crystal Structure of DL-Valinium Tetrafluoroantimonate(III) Monohydrate

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of an antimony(III) fluoride complex of the composition (C5H12NO2)SbF4·H2O (I) involving a cation of α-amino isovaleric acid (DL-valine, Val) is determined. Crystals are monoclinic: a = 12.2024(2) Å, b = 6.1636(1) Å, c = 15.5167(3) Å, Z = 4, space group P21/c. The structure is formed of DL-valinium (C5H12NO2)+ cations, complex [SbF4]nn− anions having a polymeric chain structure, and crystallization water molecules. The [SbF4]nn− complex anions consist of trigonal SbF4E bipyramids joined together by asymmetric bridging Sb–F(3)···Sb bonds. The structural units are organized into a threedimensional framework via N–H···F, N–H···O, and O–H···F hydrogen bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. N. Bolotin, N. N. Bukov, V. A. Volynkin, and V. T. Panyushkin. Coordination Chemistry of Natural Amino Acids [in Russian], Izd. LKI, Moscow, 2008.

    Google Scholar 

  2. Yu. A. Buslaev and R. L. Davidovich. Koord. Khim., 1989, 15(11), 1444.

    CAS  Google Scholar 

  3. T. N. Sumarokova, R. A. Kuidina, and L. V. Levchenko. Zh. Obshch. Khim., 1969, 39(9), 2037.

    CAS  Google Scholar 

  4. R. L. Davidovich, V. B. Logvinova, L. A. Zemnukhova, et al. Koord. Khim., 1991, 17(10), 1342.

    CAS  Google Scholar 

  5. A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva, et al. Russ. J. Coord. Chem., 2005, 31(4), 225–229.

    Article  CAS  Google Scholar 

  6. A. A. Udovenko, R. L. Davidovich, L. A. Zemnukhova, et al. J. Struct. Chem., 2010, 51(3), 540–544.

    Article  CAS  Google Scholar 

  7. A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, et al. J. Struct. Chem., 2010, 51(5), 904–908.

    Article  CAS  Google Scholar 

  8. A. A. Udovenko and L. M. Volkova. Koord. Khim., 1981, 7(12), 1763.

    CAS  Google Scholar 

  9. L. A. Zemnukhova. Synthesis, NQR Spectroscopy, and Structure of the Coordination compounds of Antimony(III), Bismuth(III), Indium(III), and Tellurium(IV). Diss. … Dr. of Chem. Sc. [in Russian], Vladivostok: Institute of Chemistry, Far Eastern Branch, RAS, 1998.

    Google Scholar 

  10. L. A. Zemnukhova, R. L. Davidovich, A. A. Udovenko, et al. Russ. J. Coord. Chem., 2005, 31(2), 115–120.

    CAS  Google Scholar 

  11. SMART and SAINT, Plus. Versions 5.0. Data Collection and Processing Software for the Smart System. Bruker AXS Inc. Madison, (WI, USA), 1998.

  12. G. M. Sheldrick. SHELXTL/PC. Versions 5.0. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data. Bruker AXS Inc. Madison, (WI, USA), 1998.

    Google Scholar 

  13. R. Gillespie, and I. Hargittai. The VSEPR of Molecular Geometry, Allyn and Bacon Boston, 1991.

    Google Scholar 

  14. G. B. Bokii. Crystal Chemistry [in Russian], Nauka, Moscow, 1971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    A. A. Udovenko, N. V. Makarenko, E. V. Kovaleva & L. A. Zemnukhova

Authors
  1. A. A. Udovenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Makarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Kovaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Zemnukhova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Udovenko.

Additional information

Original Russian Text © 2018 A. A. Udovenko, N. V. Makarenko, E. V. Kovaleva, L. A. Zemnukhova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 7, pp. 1712–1716, September-October, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Udovenko, A.A., Makarenko, N.V., Kovaleva, E.V. et al. Crystal Structure of DL-Valinium Tetrafluoroantimonate(III) Monohydrate. J Struct Chem 59, 1653–1657 (2018). https://doi.org/10.1134/S0022476618070181

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476618070181

Keywords

Search

Navigation