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In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]

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Abstract

In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH3)4][OsCl6] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry Siberian Branch, Russian Academy of Science, Novosibirsk, Russia

    T. I. Asanova, I. P. Asanov & S. V. Korenev

  2. Novosibirsk National Research University, Novosibirsk, Russia

    I. P. Asanov & S. V. Korenev

  3. Beamline Research Division, Pohang University of Science and Technology, Pohang, Republic of Korea

    M.-G. Kim

Authors
  1. T. I. Asanova
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  2. I. P. Asanov
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  3. M.-G. Kim
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  4. S. V. Korenev
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Correspondence to T. I. Asanova.

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Original Russian Text © 2017 T. I. Asanova, I. P. Asanov, M.-G. Kim, S. V. Korenev.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 5, pp. 940–949, June–July, 2017.

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Asanova, T.I., Asanov, I.P., Kim, MG. et al. In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]. J Struct Chem 58, 901–910 (2017). https://doi.org/10.1134/S0022476617050079

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  • DOI: https://doi.org/10.1134/S0022476617050079

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